Doping heteroatoms into the skeletons of parent acenes can provide more opportunities to construct novel thermally and photostable organic π-conjugated semiconductors. Herein, a family of diazole-decorated acenes (APyS and APySe) and azaacenes (PyP, PyTh, PyPy, PyPh, and PyAP) have been successfully synthesized through the classical reactions. Single-crystal X-ray analyses showed that these as-formed diazole-modified derivatives adopted a twisted topology configuration, whereas the azaacenes display reclining-chair architectures, besides a twisted structure. All these compounds displayed yellow or red light in solution. Moreover, their electrochemical behaviors were also examined. We also found that the azaacenes exhibited a positive spectroscopic response to acid.

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Enhanced understanding of historical climate impacts on crop yield is critical for adaptation and mitigations within the context of global warming. Previous impact assessments rely on statistical or process-based models, each with its own strength and weakness. To date, a global-scale comparison between process-based and statistical models in assessing climate impacts on yield vari

The interfacial mass transfer rate of a target has a significant impact on the sensing performance. The surface reaction forms a concentration gradient perpendicular to the surface, wherein a slow mass transfer process decreases the interfacial reaction rate. In this work, we self-assembled gold nanoparticles (AuNPs) in the gap of a SiO2 opal array to form a AuNP-bridge array. The diffusion paths of vertical permeability and a microvortex effect provided by the AuNP-bridge array synergistically improved the target mass transfer efficiency. As a proof of concept, we used DNA hybridization efficiency as a research model, and the surface-enhanced Raman spectroscopy (SERS) signal acted as a readout index. The experimental verification and theoretical simulation show that the AuNP-bridge array exhibited rapid mass transfer and high sensitivity. The DNA hybridization efficiency of the AuNP-bridge array was 15-fold higher than that of the AuNP-planar array. We believe that AuNP-bridge arrays can be potentially applied for screening drug candidates, genetic variations, and disease biomarkers.

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