No abstract

Two-dimensional (2D) covalent organic frameworks (COFs) have received much attention due to their tunable electronic structures and superior surface area in visible-light-driven water splitting. Compared to traditional photocatalysts, 2D COFs...

Carbon dots (CDs) with long-lived room-temperature phosphorescence (RTP) or long afterglow properties draw much attention. However, most room-temperature phosphorescent materials are metal containing, and the exploitation of long-lived color-tunable RTP materials faces great challenges. Here, we report metal-free borondoped CDs (B-CDs) for room-temperature phosphorescence with tunable color and an ultralong lifetime. B-CDs were obtained by simply calcining a mixture of boric acid and 1,3,5-benzenetricarboxylic acid in the atmosphere. The as-prepared B-CDs were characterized through UV−vis spectroscopy, photoluminescence spectroscopy, and so forth. Under the excitation of 310 nm UV light, B-CDs show RTP that appears as blue with a phosphorescence lifetime of 1042 ms, and after switching the excited wavelength to 365 nm, the RTP appears as green with a phosphorescence lifetime of 590 ms. Due to the unique RTP properties, B-CDs display promising applications in anticounterfeiting and information encryption.

Organic cathode materials are attractive for rechargeable lithium-ion batteries due to their advantages in sustainability and designability of molecular structure as well as the high upper limit of theoretical capacity....

We prepare a bipolar naphthoquinone-based small molecule DNQPA in high yield and purity by a solvent-free method, which shows exceptional cycling stability and excellent specific capacity as a cathode material when compounded with graphene.