TiO2 and SiO2 are very useful materials for building biointerfaces. A particularly interesting aspect is their interaction with lipid bilayers. Many past research efforts focused on phosphocholine (PC) lipids, which form supported lipid bilayers (SLB) on SiO2 at physiological conditions but are adsorbed as intact liposomes on TiO2. Low pH was required to form PC SLBs on TiO2. This work intends to understand the surface forces and chemistry responsible for such differences. Two charge neutral lipids: 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 2-((2,3-bis­(oleoyloxy)­propyl)­dimethylammonio)­ethyl ethyl phosphate (DOCPe) and two negatively charged lipids: 1,2-dioleoyl-sn-glycero-3-phospho-l-serine (DOPS) and 2-((2,3-bis­(oleoyloxy)­propyl)­dimethylammonio)­ethyl hydrogen phosphate (DOCP) were used. Using calcein leakage assays, adsorption measurement, cryo-TEM, and washing, we concluded that charge is the dominating factor on SiO2. The two neutral lipids form SLB on SiO2 at pH 3 and 7, but the two negatively charged ones cannot form. On TiO2, both charge and coordination chemistry are important. The two anionic lipids formed SLB from pH 3 to 10. DOCP had stronger affinity than DOPS likely due to the tighter terminal phosphate binding of the former. The two neutral liposomes formed SLB only at pH 3, where phosphate interaction and van der Waals force are deemed important. The pH 3 prepared TiO2 DOPC SLBs are destabilized at neutral pH, indicating the reversible nature of the interaction. This work has provided new insights into two important materials interacting with common liposomes, which are important for reproducible biosensing, device fabrication, and drug delivery applications.

A new, convenient and efficient AgNO 3 -catalyzed strategy for the preparation of 2-(benzo[d]azol-2-yl)phenol derivatives in good to excellent yields (63-98%) is described. The reaction proceeds via condensation/intramolecular nucleophilic addition/oxidation process between substituted salicylaldehydes and 2-aminothiophenol, 2-aminophenol or benzene-1,2-diamine under mild reaction conditions. Notably, this reaction utilizes cheap AgNO 3 as a readily available and low-cost benign oxidant at low catalyst loadings with excellent functional group tolerance.

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A new microwave energy reception method is proposed for the wireless energy transmission needs of lunar rovers combined with the lunar environment, i.e. collecting thermal energy through microwave absorbing materials, and then converting thermal energy into direct current by using temperature difference power generation devices. The article analyses the two conversion processes, microwave-thermal and thermal-DC, separately. Under the approximate condition that the temperature at both ends of the absorbing material is regarded as equal, the two conversion processes are linked by energy conservation, which theoretically leads to the temperature and total efficiency of the system at steady state. The temperature and total efficiency of the system are initially obtained by numerical simulation with respect to the thickness of the absorbing material, the receiving area and the input power density by selecting the parameters of the carbon and iron composite material at 10 GHz. The results show that there is an optimum thickness of absorbing material for a certain input power density and receiving area, which results in the highest system efficiency. The larger the receiving area and input power density in a certain range, the higher the efficiency, but beyond a certain range the system efficiency shows a decreasing trend. Also the theory and the actual will produce a large deviation when temperature is high. The article concludes that this energy receiving method has great potential for application in the space environment based on the excellent wave absorbing materials and thermoelectric components but further research is needed.