Effective and reliable encapsulation of phase change materials (PCMs) is essential and critical to the high‐performance solar‐thermal energy harvesting and storage. However, challenges remain pertaining to manufacturing scalability, high efficiency in energy storage/release, and anti‐leakage of melted PCMs. Herein, inspired by natural legume, a facile and scalable extrusion‐based core‐sheath 3D printing strategy is demonstrated for directly constructing bean‐pod‐structured octadecane (OD)/graphene (BOG) phase change microlattices, with regular porous configuration as well as individual and effective encapsulation of OD “beans” into highly interconnected graphene network wrapping layer built by closely stacked and aligned graphene sheets. The unique architectural features enable the ready spreading of light into the interior of phase change microlattice, a high transversal thermal conductivity of 1.67 W m−1 K−1, and rapid solar‐thermal energy harvesting and transfer, thereby delivering a high solar‐thermal energy storage efficiency, and a large phase change enthalpy of 190 J g−1 with 99.1% retention after 200 cycles. Most importantly, such encapsulated PCMs feature an exceptional thermal reliability and stability, with no leakage and shape variation even at 1000 thermal cycles and partial damage of BOG. This work validates the feasibility of scalably printing practical encapsulated PCMs, which may revolutionize the fabrication of composite PCMs for solar‐thermal energy storage devices.

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