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Fe 71 Si 16 B 9 Cu 1 Nb 3 amorphous alloy ribbons were prepared with a single roll polar method. X-ray diffraction analysis of the surface samples was completely amorphous. The thermal stability parameters T x , T p , and T end of amorphous ribbons were measured with a synchronous thermal analyzer under high purity argon gas and analyzed for their crystallization behavior. The heating rate was 10 K min −1 , 15 K min −1 , 20 K min −1 , and 30 K min −1 . The T x and T p of the Fe 71 Si 16 B 9 Cu 1 Nb 3 amorphous alloy increased with an increase in the heating rate, indicating that the crystallization behavior has a kinetic effect. The crystallization activation energy of the amorphous alloy was calculated using the Kissinger and Ozawa equations, respectively. The calculation results of the two methods were consistent. The sample was annealed (761 K, 786 K, 801 K, and 858 K, holding for 300 s) under the protection of high purity argon. The phase transition and microstructure transformation of the amorphous alloy during isothermal crystallization were analyzed by x-ray diffraction. When the alloy was annealed at 801 K, a single α-Fe(Si) solid solution precipitated on the amorphous matrix. Magnetic properties were measured using a vibrating sample magnetometer and observed by transmission electron microscopy. When the alloy was annealed at 786 K and 801 K, the saturation magnetic induction reached 1.22∼1.27 T, coercivity was as low as 5.3∼7.2 A m −1 , and the average grain size was about 10∼20 nm.

The viscosities of metallic glasses gradually drop with temperature rising in their supercooled liquid region (SLR) which enables them to be thermoplastically formed and totally overturns the processing method of traditional metallic materials: their forming can be realized under temperature and stress far below those of traditional metallic materials. Based on this property, metallic glasses are considered as the ideal miniature fabrication materials due to their unique amorphous structures and no crystalline defects such as dislocation and grain boundary.The thermoplastic micro forming of metallic glasses in their SLR is studied in the present paper. A universal equation which describes the filling kinetics of viscous metallic glasses in the non-circular channel is proposed with the help of fluidic mechanics, and the results may be theoretically useful for the micro application of metallic glasses.In addition, some applications in the micro thermoplastic forming of metallic glasses are introduced. A metallic glass mold insert for hot embossing of polymers is fabricated by the micro thermoplastic forming of metallic glass, and it is found to have many advantages in mechanical property, fabrication efficiency, surface quality, etc. compared with the traditional material and method. A similar approach is used to fabricate gratings, which may provide a new material and technology to produce gratings. The superhydrophobic metallic glass surface with excellent abrasion and corrosion resistance is also fabricated by constructing micro-nano hierarchical structures on metallic glass surface. The bulk metallic glass micro fuel cell is also finished and found to have good performance.

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