A flexible, transparent, chemical gas sensor is assembled from a transparent conducting film of carbon nanotube (CNT) networks that are coated with hierarchically nanostructured polyaniline (PANI) nanorods. The nanocomposite film is synthesized by in-situ, chemical oxidative polymerization of aniline in a functional multiwalled CNT (FMWCNT) suspension and is simultaneously deposited onto a flexible polyethylene terephthalate (PET) substrate. An as-prepared flexible transparent chemical gas sensor exhibits excellent transparency of 85.0% at 550 nm using the PANI/FMWCNT nanocomposite film prepared over a reaction time of 8 h. The sensor also shows good flexibility, without any obvious decrease in performance after 500 bending/extending cycles, demonstrating high-performance, portable gas sensing at room temperature. This superior performance could be attributed to the improved electron transport and collection due to the CNTs, resulting in reliable and efficient sensing, as well as the high surface-to-volume ratio of the hierarchically nanostructured composites. The excellent transparency, improved sensing performance, and superior flexibility of the device, may enable the integration of this simple, low-cost, gas sensor into handheld flexible transparent electronic circuitry and optoelectronic devices.
Integrated optical power splitters are one of the fundamental building blocks in photonic integrated circuits. Conventional multimode interferometer-based power splitters are widely used as they have reasonable footprints and are easy to fabricate. However, it is challenging to realize arbitrary split ratios, especially for multi-outputs. In this Letter, an ultra-compact power splitter with a QR code-like nanostructure is designed by a nonlinear fast search method. The highly functional structure is composed of a number of freely designed square pixels with the size of 120×120 nm which could be either dielectric or air. The light waves are scattered by a number of etched squares with optimized locations, and the scattered waves superimpose at the outputs with the desired power ratio. We demonstrate 1×2 splitters with 1:1, 1:2, and 1:3 split ratios, and a 1×3 splitter with the ratio of 1:2:1. The footprint for all the devices is only 3.6×3.6 μm. Well-controlled split ratios are measured for all the cases. The measured transmission efficiencies of all the splitters are close to 80% over 30 nm wavelength range.
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