Operando tracking the chemical dynamics/states of a battery and its components is critical to their second life for boosting their sustainability. Herein, we demonstrate the feasibility and diversity of the...

Understanding ion transport kinetics and electrolyte-electrode interactions at electrode surfaces of batteries in operation is essential to determine their performance and state of health. However, it remains a challenging task to capture in real time the details of surface-localized and rapid ion transport at the microscale. To address this, a promising approach based on an optical fiber plasmonic sensor capable of being inserted near the electrode surface of a working battery to monitor its electrochemical kinetics without disturbing its operation is demonstrated using aqueous Zn-ion batteries as an example. The miniature and chemically inert sensor detects perturbations of surface plasmon waves propagating on its surface to rapidly screen localized electrochemical events on a sub-μm-scale thickness adjacent to the electrode interface. A stable and reproducible correlation between the real-time ion insertions over charge-discharge cycles and the optical plasmon response has been observed and quantified. This new operando measurement tool will provide crucial additional capabilities to battery monitoring methods and help guide the design of better batteries with improved electro-chemistries.

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We demonstrate the generation of versatile mode-locked operations in an Er-doped fiber laser with an indium tin oxide (ITO) saturable absorber (SA). As an epsilon-near-zero material, ITO has been only used to fashion a mode-locked fiber laser as an ITO nanoparticle-polyvinyl alcohol SA. However, this type of SA cannot work at high power or ensure that the SA materials can be transmitted by the light. Thus, we covered the end face of a fiber with a uniform ITO film using the radio frequency magnetron sputtering technology to fabricate a novel ITO SA. Using this new type of SA, single-wavelength pulses, dual-wavelength pulses, and triple-wavelength multi-pulses were achieved easily. The pulse durations of these mode-locked operations were 1.67, 6.91, and 1 ns, respectively. At the dual-wavelength mode-locked state, the fiber laser could achieve an output power of 2.91 mW and a pulse energy of 1.48 nJ. This study reveals that such a proposed film-type ITO SA has excellent nonlinear absorption properties, which can promote the application of ITO film for ultrafast photonics.

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