High-performance microporous activated carbon (AHC) for CO2 capture was prepared from an emerging marine pollutant, Sargassum horneri, via hydrothermal carbonization (HTC) and KOH activation. The as-synthesized carbon material was characterized by N2 sorption-desorption measurement, TGA, SEM, XRD, FTIR, and elemental analysis. Impressively, the activated carbon exhibited high specific surface area (1221 m2/g), narrow distributed micropores (∼0.50 nm), and a relatively high nitrogen content (3.56 wt.%), which endowed this carbon material high CO2 uptake of 101.7 mg/g at 30°C and 1 bar. Moreover, the carbon material showed highly stable CO2 adsorption capacity and easy regeneration over four adsorption-desorption cycles. Two kinetic models were employed in this work and found that the pseudo-first-order kinetic model (R2 = 0.99) provided the best description. In addition, the high CO2 uptake is mainly attributed to the presence of abundant narrow microporous. The macroporous structure of hydrochar (HC) played an important role in the production of microporous carbon with high adsorption properties. This work provides an efficient strategy for preparing microporous activated carbon from Sargassum horneri, and AHC is a promising candidate acting as an efficient CO2 adsorbent for further industrial application.
Solid acid catalysts were synthesized from macroalgae Sargassum horneri via hydrothermal carbonization followed by sulfuric acid sulfonation. A three-variable Box-Behnken design and optimization was used to maximize surface acidity. The optimal preparation conditions were found to be at the carbonization temperature of 217 °C, the carbonization time of 4.6 h and the sulfonation temperature of 108.5 °C. Under these conditions, the highest surface acidity achieved was 1.62 mmol g −1 .Physical and chemical properties of prepared solid acid catalyst were characterized by powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, and elemental analysis. The results proved the grafting of -SO 3 H groups on an amorphous carbon structure. The catalyst activity was evaluated by the esterification of oleic acid with methanol. The sample prepared achieved 96.6% esterification yield, which was higher than the 86.7% yield achieved by commercial Ambersyst-15 under the same reaction conditions. Graphical Abstract
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