Abstract. Aerosol particles in the atmosphere are important participants in the formation of cloud droplets and have significant impact on cloud albedo and global climate. According to the Köhler theory which describes the nucleation and the equilibrium growth of cloud droplets, the surface tension of an aerosol droplet is one of the most important factors that determine the critical supersaturation of droplet activation. In this paper, with specific interest to remote marine aerosol, we predict the surface tension of aerosol droplets by performing molecular dynamics simulations on two model systems, the pure water droplets and glycine in water droplets. The curvature dependence of the surface tension is interpolated by a quadratic polynomial over the nano-sized droplets and the limiting case of a planar interface, so that the so-called Aitken mode particles which are critical for droplet formation could be covered and the Köhler equation could be improved by incorporating surface tension corrections.
Hydrophobic surfaces have gained extensive attention in recent decades for their potential applications. The hydrophobic properties of dragonfly's (Pantala flavescens) wings were measured, and the water contact angles (WCAs) of the distal and basal part of a dragonfly's wing were 134.9 and 125.8 , respectively. Images obtained by optical microscopy and scanning electron microscopy showed the microstructures and nanostructures on the wing surface. Microstructures appeared as cell block patterns, and the size of the blocks decreased from the basal to distal part. However, no significant differences of chemical composition between the two parts were detected by X-ray photoelectron spectroscopy. To understand the correlation between the structures and WCA, a double roughness structure model was built theoretically with simplified lattice patterns, and the theoretical model was well fitted with empirical wettability of the dragonfly's wing.
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