In this paper, ions i.e. Cu2+, Pb2+and Cd2+ were absorbed by the amphoteric bagasse hemicelluloses, and the influences of pH value, adsorption time and the initial concentration of metal ion have been studied. The results show that the optimal adsorption pH values for Cu2+, Pb2+ and Cd2+ are 6.5, 6.0 and 7.5, respectively. The adsorption capacity to ions Cu2+, Pb2+ and Cd2+ reaches the maximum values when the adsorption time is 180 min. Net adsorption to ions Cu2+, Pb2+ and Cd2+ increases with increasing the initial concentration of the metal ions. Analysis results of adsorption dynamics show that the adsorption of Cu2+, Pb2+ and Cd2+ follows Ho 's Pseudo second-order kinetics linear model. It can be seen from the adsorption isothermal research that absorption of the amphoteric bagasse hemicelluloses to ions Cu2+, Pb2+and Cd2+ can be well described by the Langmuir isotherm linear model. Moreover, the theoretical values of the maximum absorption capacity qmax for ions Cu2+, Pb2+ and Cd2+ were determined to be 21.98 mg/g, 81.97 mg/g and 31.85 mg/g, respectively.
The bagasse fibers were activated by alkalize and etherified. 1,2-ethanediamine and carbon disulfide were used to modify the etherify fiber to get the chelate-fiber contained sulfur and nitrogen. The FTIR was used to characterize the xanthated aminating-fiber (XAF). The mechanism of sorption properties for heavy metal ions were studied. As the results shown, the optimal process to prepare the XAF was that the reaction time, concentration of NaOH and dosage of CS2 was 60min, 12% and 2mL, respectively. The chelate-fiber containing sulfur and nitrogen possessed high adsorption capacities for Cu(II) and the mechanism of sorption fitted the pseudo-second-order model well.
In this paper, ions i.e. Cu2+, Pb2+and Cd2+ were absorbed by the carboxyl bagasse hemicelluloses, and the influences of pH value, adsorption time and the initial concentration of metal ion have been studied. The results show that the optimal adsorption pH values for Cu2+, Pb2+and Cd2+ are 5.5, 5.5 and 7.5, respectively. The adsorption capacity to ions Cu2+, Pb2+and Cd2+ reaches the maximum values when the adsorption time is 180 min. Net adsorption to ions Cu2+, Pb2+and Cd2+ increases with increasing the initial concentration of the metal ions. Analysis results of adsorption dynamics show that the adsorption of Cu2+, Pb2+and Cd2+ follows Ho 's Pseudo second-order kinetics linear model. It can be seen from the adsorption isothermal research that absorption of the carboxyl bagasse hemicelluloses to ions Cu2+, Pb2+and Cd2+ can be well described by the Langmuir isotherm linear model. Moreover, the theoretical values of the maximum absorption capacity qmax for ions Cu2+, Pb2+and Cd2+ were determined to be 20.28 mg/g, 82.64 mg/g and 30.58 mg/g, respectively.
Sugarcane bagasses were used as raw materials to produce the hemicelluloses, and the effects of temperature, alkali consumption, time and liquid to solid ratio on the extraction yield of hemicelluloses were investigated. Through the analysis of the response surface method, results were concluded that the best extraction process conditions were as follows: NaOH concentration 10.60%, extraction time 4.34 h, solid-liquid ratio 1:40.59, actual extraction rate is 31.486%, corresponding to the model prediction 31.4447% basically.
Fenton-flocculation process as one of effective the advanced oxidation treatments was widely used and studied. In this paper, the efficiency of Fenton oxidation was evaluated by the velocity ratio of CODcr decreased to Fenton reagent consumed. The coagulant aids, PAC and PAM, were canalized by CODcr removal rate, transmittance of the supernatant, the flocculation ratio and sludge settling ratio in Fenton-flocculation process. As the results shown, comparing with flocculation by Fenton reagent, transmittance of the supernatant and flocculating ratio can reach 50% and 80% respectively. The optimal dosage of coagulant aids is PAC 60 mg/L or PAM 4mg/L. The efficiency of Fenton oxidation is decreased but not be increased by adding more Fenton reagent in the advanced treatment of waste water.
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