Linear and angular benzobisoxadisiloles 14 and 16 can serve as the precursors for stepwise generations of the syntetic equivalents of 1,4- and 1,3-benzdiynes. Benzynes generated were trapped as [4+2] cycloaddition products. Two identical or different rings can be fused to the benzdiyne equivalents. Highly substituted arenes were obtained by removing the oxygen bridges from the furan adducts. The synthesis of naphthoxadisilole 28, which can serve as the precursor of 2,3-naphthyne, is also described.
In this paper, Ground deformation in shield tunneling construction is researched. It is put forward that ground deformation is caused by three reasons, which are ground loss, the positive thrust and the friction. By solving the three-part respectively, the three-dimensional solution formula can be obtained after superposing these. This method is used to calculate the tunnel construction phase at any point in the level of vertical settlement and horizontal displacement. As shown in analytical calculation, the predicted ground displacements of this method are in good agreement with the measured values.
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