Microwave absorbents play a vital role in governing the monomeric products from lignin during the microwave-assisted depolymerization (MAD) process. The influence of various microwave absorbents on the conversion efficiency and lignin monomeric products in a dynamic vapor flow reaction system was investigated. Results showed that the selected microwave absorbents could linearly and rapidly heat lignin from 200 to 500 °C within 8 min under a microwave power of 1000 W. The yields of liquid products, guaiacols, and phenols were increased linearly with the heating rate (°C/min). The high microwave absorptivity of absorbents promoted the formation of liquid products and phenolic compounds. To offer further support, the use of MoS 2 with a very high microwave absorptivity (185.0 °C/min) showed very high yields of liquid products (34.1 wt %) and phenolics (32.1 wt %). This work provided an effective methodology to enhance the lignin conversion efficiency to monomeric products using microwave absorbents.
We combine biodegradable plastic (polyvinyl alcohol/glycerol polymer), and cellulose-based tissue paper in a very short time (5 s) by a facile way to form a new matrix, named plastic-paper, which has high optical transmittance (~89%) and high optical haze (~90%) in broadband. Results showed that the plastic-paper is durable in different solvents, with high folding strength (over 3500 folding times) and good mechanical strength (>30 MPa tensile strength). Interestingly, the plastic-paper presents a two-sidedness of surface morphology. The rough side shows high light transmittance and the smooth side presents high optical haze. The smooth side of the plastic-paper is successfully applied to Organic Light-Emitting Diode (OLED). When the rough surface of plastic-paper is used in solar cells, the maximum output power increases by 2.6% compared with bare solar cells. The developed plastic-paper with high optical transmittance and high optical haze holds a great potential in flexible optoelectronic devices.
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