Polyacrylamide (PAM)-based microspheres
are commonly used as water
plugging and profile control agents, but the poor mechanical strength
and few studies on the dispersion stability, both of which are closely
related to the profile control performance, limit the application
of microspheres. Herein, we synthesize nanoscale PAM-based copolymer
hydrogel microspheres with an inverse microemulsion copolymerization
of acrylamide (AM) and 2-methyl-2-acrylic amide propyl sulfonic acid
(AMPS) in the presence of vinyl-functionalized silica nanoparticles
(VSNPs). The results show that a small amount of VSNPs (1.0 wt %)
increases the compressive strength of the hydrogel by 0.6 times. The
swollen nanoscale PAM/silica hydrogel microspheres show good dispersion
stability. VSNPs significantly improve the elasticity of the hydrogel
microspheres, and their dispersion stability under high temperature
and high-salinity conditions. The simulation evaluation of core plugging
suggests that the plugging rate of PAM-based polymer/silica hybrid
microspheres with addition of 0.7 wt % VSNPs increases from 80% to
92% compared to neat polymer microspheres. This work provides a novel
design of nanoscale cross-linked microspheres for deep profile control
in different geological environments.
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