Organometal halide perovskites have recently emerged as outstanding semiconductors for solid-state optoelectronic devices. Their sensitivity to moisture is one of the biggest barriers to commercialization. In order to identify the effect of moisture in the degradation process, here we combined the in situ electrical resistance measurement with time-resolved X-ray diffraction analysis to investigate the interaction of CH3NH3PbI(3-x)Cl(x) perovskite films with moisture. Upon short-time exposure, the resistance of the perovskite films decreased and it could be fully recovered, which were ascribed to a mere chemisorption of water molecules, followed by the reversible hydration into CH3NH3PbI(3-x)Cl(x)·H2O. Upon long-time exposure, however, the resistance became irreversible due to the decomposition into PbI2. The results demonstrated the formation of monohydrated intermediate phase when the perovskites interacted with moisture. The role of moisture in accelerating the thermal degradation at 85 °C was also demonstrated. Furthermore, our study suggested that the perovskite films with fewer defects may be more inherently resistant to moisture.

We present a high-peak-power, near-infrared laser system based on optical parametric chirped pulse amplification pumped by a home-built picosecond pumping laser, which can generate over 40 mJ energy at 1450 nm center wavelength and operate at 100 Hz repetition rate. Subsequently, the chirped laser pulses are compressed down to 60 fs with 26.5 mJ energy, corresponding to a peak power of 0.44 TW. This high-energy, long-wavelength laser source is highly suitable for driving various nonlinear optical phenomena, such as high-order harmonic generation and high-flux coherent extreme ultraviolet/soft X-ray radiation.

The generation of high-peak-power, few-cycle mid-infrared (MIR) pulses using coherent beam combination and nonlinear pulse compression techniques simultaneously is demonstrated. The two pulses, with identical pulse energy of 2.8 mJ and pulse duration of 160 fs, are coherently combined at the input end of a krypton-filled hollow-core fiber (HCF), and then the bandwidth of the combined pulse is broadened to near an optical octave due to strong phase modulations, and the temporal width is compressed into a few-cycle regime. Finally, a 2.7 mJ, 22.9 fs, 20 Hz laser at 4 μm can be obtained, and the pulse peak power is greatly enhanced compared with that of conventional single-channel optical parametric chirped pulse-amplification systems. Furthermore, the peak power generated from this system has the prospect of further scaling up through use of more channels of coherent combination, which can pave a way to generate higher peak power ultra-intense MIR pulses for strong-field physics.