A comparable study of the microstructure and magnetic properties was performed for magnetite films deposited on (100)-oriented MgO and SrTiO3 (STO) substrates. The growth of strained high quality Fe3O4 films was confirmed by x-ray diffraction analysis and Raman spectroscopy measurements. The surface morphology and magnetic properties of the two films were found to be obviously different. Moreover, a stripelike magnetic domain structure was observed in the film on STO. Substrate-induced strain is believed to be responsible for these observations, which significantly affects the magnetic anisotropy and the magnetic coupling at the antiphase boundaries in the films.

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The surface with the gradient non-wettability intensely appeals to researchers because of its academic significance and applications for directional droplet movement. Herein, we developed a homogeneous structure superhydrophobic surface with the gradient non-wettability by a combination strategy of chemical etching and vapor diffusion modification. As a consequence, the as-prepared surface exhibits a remarkable gradient characteristic of water repellency, and the water contact angle is mainly located within the range of 162 ± 0.5 to 149 ± 0.4°. Meanwhile, the sliding angle also exhibits a corresponding change from 3 to 11°. On this basis, the gradient characteristic of non-wettability induces the distinguishing droplet adhesion on the surface, that is, from 19 μN for the most hydrophobic end to 57 μN for the opposite one. Because of the difference of the water adhesion force, droplets on the as-prepared surface can well roll alongside a specific direction (i.e., gradient direction of nonwettability). In terms of dynamic impact droplets, they can rapidly rebound off the sample surface with the short contact time of 12.8 ms, and the finally fallen droplets mainly deviate toward weaker regions because of water repellency. To analyze this phenomenon, it is found that the asymmetric mechanic behavior is mainly caused by the unbalanced retraction force between the both ends of the impact droplet. This work provides a novel strategy to construct the homogeneous structure superhydrophobic surface with the gradient non-wettability for the applications in the droplet movement control or transport.

Ice accumulation on various surfaces in low-temperature and high-humidity environments is still a major challenge for several engineering applications. Herein, we fabricated a kind of PDMS coating with the introduction of porous structures under the surface by a two-step curing and phase separation method. The coatings with no further surface modification showed good hydrophobicity and icephobicity, and the typical ice adhesion strength was down to 40 kPa with a water contact angle of 116.5°. More than that, the porous PDMS coatings showed extraordinary icephobicity, especially toward large-scale ice (>10 cm2). In this case, the large-scale ice layer can be rapidly removed under a small external deicing force in a form of interface crack propagation rather than whole direct fracture. It was confirmed that by regulating the pore size and porosity of PDMS coatings properly, the stiffness mismatch between coatings and ice can be controlled to induce the initiation of interfacial cracks. On this basis, under the condition of a large-scale icing area, a small external deicing force can cause an increased surface stress concentration, and the formed interface cracks can propagate quickly, resulting in the ice layer falling off easily. In addition, under the influence of the size effect, ice can be removed without an additional force, and the minimum external force (per unit width) can be only 60 N/cm. This paper proposes that prefabricating a large number of microcracks at the interface can significantly weaken the bonding between ice and coatings, that is, reduce the fracture toughness. The new coatings have a remarkable effect toward large-scale icing.