Solar-driven
interfacial steam generation (SDISG), as an emerging
green and renewable approach to overcome water shortage, is very suitable
for remote locations, developing countries, and disaster zones because
it does not require an additional energy supply. However, the traditional
metal-based and carbon-based absorbers always suffered from fragility
(or rigidity) and the complex preparation process, which dramatically
inhibited their transportation and installation in areas with poor
infrastructure. Therefore, there is an urgent need to develop a universal
method to fabricate flexible solar evaporators. Herein, a novel solar
evaporator that integrates a flexible matrix (Cu mesh or textile)
and a hierarchical Fe-MOF-74 photothermal absorber component is perfectly
prepared for the rapid and efficient SDISG. Notably, the results show
that Fe-MOF-74-based flexible textile matrix composites exhibit outstanding
light absorption (83.81%), low thermal conductivity (0.1730 W/m K),
super hydrophilic properties (within 50 ms, the contact angle is close
to 0°), excellent salt resistance, high evaporation rate (1.35
kg/m2 h), and photothermal conversion efficiency (η
is 81.5% under one sun, stable for 30 days). Owing to the flexibility,
recyclability, and above-mentioned excellent performance, the prepared
hierarchical Fe-MOF-74-based flexible composite systems are more practical
for transportation, large-scale production, and stable and efficient
applications. As a result, this work offers new insight into the future
development of the combination of a MOF-based photothermal absorber
and flexible substrates, as well as for the application of interfacial
solar seawater desalination, and provides a new reference for other
applications.
The development of efficient, stable, and cost‐effective heterogeneous catalysts for catalytic transfer hydrogenation (CTH) of biomass‐derived furfural (FAL) is highly desired. Herein, series of N‐doped graphitic carbon embedded CoNi bimetallic alloy nanoparticles were fabricated and used for the CTH of FAL to value‐added furfuryl alcohol (FOL) with renewable isopropanol as hydrogen donor. Intrinsic catalytic activity examination indicated the catalytic performance of NixCoy@NGC (x:y=1 : 3, 1 : 1, 3 : 1) nanocatalysts were sensitive to their chemical compositions. The optimal Ni1Co1@NGC nanocatalyst with Ni/Co mole ratio of 1 : 1 afforded a largest FOL yield of 89.3% with nearly full conversion of FAL. The synergistic effect enabled by bimetallic alloys and the abundant N‐based Lewis base sites and surface Co−N active species were revealed based on systematic structural characterization, responsible for the excellent catalytic efficiency of bimetallic Ni1Co1@NGC nanocatalyst for CTH of FAL.
Solar steam generation technology is considered to be one of the most promising seawater desalination. To achieve a high and stable water production rate, absorber structure and salt deposition are...
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