FeCl 3 . 6H 2 O-catalysed Mizoroki-Heck reactions of aryl iodides with methyl acrylate have been achieved by using 2,2'diamino-6,6'-dimethylbiphenyl as the ligand and NaHCO 3 as the base in DMF and H 2 O. It was found that an appropriate amount of H 2 O is essential for high yields in these reactions.
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