In the era of big data, smart cities have become a promising prospect for governments, citizens, and industrials. Many ideas and their derived systems for smart cities depend on big data for achieving a goal of data intelligence. However, there is an urgent transformation trend from data intelligence to service intelligence in the vision of smart cities due to the living requirements of citizens. People-centric service intelligence in smart cities has to support the realization of people’s needs within urban and social domains. This paper introduces a concept of people-centric service intelligence, defines the level of it and its challenges in the aspect of infrastructure, human dynamics, human understanding and prediction, and the human–machine interface. Then, this paper proposes the theoretical framework and technical frameworks of people-centric service intelligence, and the service intelligence schemas for future construction of smart cities. It will be helpful for governments and industries to design people-centric service intelligence for improving the quality of life, the capabilities of good sustainability, and better development.

To understand the molecular mechanism of ovule development, a MADS box gene, HoMADS 1 , has been isolated from the ovule tissues of Hyacinthus . Sequence comparison showed that HoMADS 1 is highly homologous to both class C and D genes. Furthermore, phylogenetic analysis suggests that HoMADS 1 is most likely a class D MADS box gene. RNA hybridization revealed that HoMADS 1 was exclusively expressed in the ovules. Over-expressing HoMADS 1 in transgenic Arabidopsis plants produced ectopic carpelloid structures, including ovules, indicating that HoMADS 1 is involved in the determination of carpel and ovule identities. Interestingly, during in vitro flowering, no HoMADS 1 mRNA was detected in the floral tissues at high level hormones in the media. However, HoMADS 1 mRNA accumulated in the floral tissues when the regenerated flowers were transferred to the media containing low level hormones which could induce in vitro ovule formation. Our data suggest that the induction of HoMADS 1 by plant hormones may play important roles during ovule initiation and development in the regenerated flower. Whether HoMADS 1 expression is also regulated by cytokinin and auxin during ovule development in planta remains to be investigated.

Although great progress has been made in hybrid iodocuprates(i) as lighting phosphors, the effects of aromatic and aliphatic structure directing agents (SDAs) on their water stability, structure and photoluminescence (PL) properties are still not clear. Herein, aromatic N-heterocyclic 1,2-di(4-pyridyl)ethylene (dpe), aliphatic N-heterocyclic 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu) and N-aminoethylpiperazine (app) were selected to be SDAs to construct two types of hybrid iodocuprates(i) via a facile in situ approach. Aromatic dpe-derived cations are successfully directed to form (Medpe)(CuI) (1), (Medpe)(CuI) (2), (Etdpe)(CuI) (3), and (Hdpe)(CuI) (4). Three of them contain unprecedented inorganic iodocuprate clusters or chains. The aliphatic N-heterocyclic dbu- and app-derivative cations are responsible for the formation of (Hdbu)(CuI) (5) and (Happ)(CuI)·2I·2HO (6), which contain a (CuI) chain and a (CuI) binuclear cluster, respectively. For the first time, the influence mechanisms of the water stabilities of iodocuprate-based PL materials were disclosed, by analyzing the possible interactions between SDAs and water molecules. 1-2 are PL silent due to their "self-quenching effect". 3, 4 and5 exhibit bright red, orange and yellow solid-state PL emissions at room temperature respectively, originating from the charge transfer between inorganic iodocuprate species and organic N-heterocycles. The co-template approach leads to multiple charge transfers in 6, which features a tunable PL behavior from bluish green to white by varying the excitation light, and has a quantum yield up to 43% (the highest value among hybrid iodocuprates containing (CuI) clusters). The comparative study not only helps us to rationally synthesize iodocuprate-based PL materials with enhanced performance, but also provides a new method to obtain wavelength-dependent PL materials.

Two types of in situ formed structure directing agents (SDAs) including aromatic triphenylphosphine (PPh)- and aliphatic piperazine (Hpp)-derivative cations were used to synthesize five new hybrid iodoargentates, namely (EtPPh)AgI (1, Et = ethyl), (n-PrPPh)AgI (2, n-Pr = n-propyl), (i-PrPPh)AgI (3, i-Pr = isopropyl), (Mepp)AgI (4, Me = methyl), and (Happ)(AgI)·2I·2HO (5, app = N-aminoethylpiperazine). A comparative study of the two types of SDAs on the structures, stabilities and properties of hybrid iodoargentates was performed in detail. Structurally, except for (EtPPh) and (n-PrPPh), which both directly form (AgI) anionic chains in 1 and 2, three SDAs generate hybrid iodoargentates different from each other with inorganic anions ranging from a 0-D (AgI) dimer to 1-D α-type (AgI) and (AgI) chains. With regard to the electronic structures, aromatic PPh-derivative cations make noticeable contributions to the bottom of the conduction bands, while aliphatic pp-derivative cations make nearly no contribution to the frontier orbitals, clearly indicating their different ways to adjust the band gaps. With regard to stability, the decomposition temperatures of 1-3 in the range of 324-349 °C are noticeably higher than the values of 217 and 225 °C for 4 and 5. Furthermore, 1-4 exhibit good water stabilities, which is ascribed to the alkylation reactions precluding the formation of strong hydrogen bonds between alkylated SDAs and extraneous HO molecules. Contrarily, the presence of typical hydrophilic [double bond, length as m-dash]NH, [triple bond, length as m-dash]NH and -NH groups on the protonated (Happ) cation makes 5 sensitive to water and a hydrolysis reaction occurs to generate a cubic AgI phase. Finally, 1-3 exhibit high photocatalytic efficiencies for the degradation of rhodamine B (RhB) dye in wastewater under visible light. All conclusions obtained here will help a lot in the synthesis of stable functional metal halide-based hybrids.