Organic solar cells (OSCs) have made dramatic advancements during the past decades owing to the innovative material design and device structure optimization, with power conversion efficiencies surpassing 19% and 20% for single‐junction and tandem devices, respectively. Interface engineering, by modifying interface properties between different layers for OSCs, has become a vital part to promote the device efficiency. It is essential to elucidate the intrinsic working mechanism of interface layers, as well as the related physical and chemical processes that manipulate device performance and long‐term stability. In this article, the advances in interface engineering aimed to pursue high‐performance OSCs are reviewed. The specific functions and corresponding design principles of interface layers are summarized first. Then, the anode interface layer, cathode interface layer in single‐junction OSCs, and interconnecting layer of tandem devices are discussed in separate categories, and the interface engineering‐related improvements on device efficiency and stability are analyzed. Finally, the challenges and prospects associated with application of interface engineering are discussed with the emphasis on large‐area, high‐performance, and low‐cost device manufacturing.
The highly luminous lanthanide metal−organic gels (Ln-MOGs) can act as fluorescent probes for the detection of organic amines and can also be used to build white-light emitting materials according to...
Uranium
is one of the principal raw materials in the nuclear industry, but
if released into the natural environment, it also poses latent health
risks to mankind. Therefore, there is an urgent need to develop a
strategy that can concurrently detect and adsorb uranium to realize
the sustainable development of nuclear power and protect the environment.
In this work, a fluorescent zinc-based metal–organic framework
(HNU-50) was designed and synthesized for the effective
detection and extraction of U(VI). The amide groups on N-pyridin-4-ylpyridine-4-carboxamide ligands and two uncoordinated
carboxyl oxygen atoms on pyromellitic acid ligands in HNU-50 provide potential uranium-binding sites. Consequently, HNU-50 is competent of selectively and efficiently catching uranyl ions,
achieving an optimum adsorption capacity of 632 mg/g. Additionally,
the adsorption of U(VI) results in fluorescence quenching of HNU-50, thus allowing sensitive and selective detection of
U(VI) by fluorescence change. Note that HNU-50 exhibits
a considerably low detection limit of 1.2 × 10–8 M for U(VI) in aqueous solution, which is below the World Health
Organization maximum pollution standards for potable water (6.3 ×
10–8 M).
Stable presence of U(V)-containing compounds is important for the study of radionuclides. However, pentavalent uranium is prone to disproportionation, thus U(V)-containing compounds are generally sensitive to air and water. Herein,...
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