By orthogonal design method, Catalytic activity of /ZrO2 solid superacid is studied, and the influence of catalyst characteristic and structure by manufacturing equipment is issued. It is concluded that the best prepared conditions of the superacid catalyst /ZrO2 for the synthesis of Octyl-Polyglycoside are followed:(1) PH=9.5; (2) calcined temperature at 500; (3) M(H2SO4)=0.5mol/L. Using this kind of catalyst the conversion of glueoside may reach as high as 96% in the synthesis of OCtyl-Polyglycoside and the selectivity is very high for the synthesis of Octyl-Polyglycoside. By introducing other metal oxide, the catalytic activity of complex solid superacid is studied.

Epoxidation of allyl chloride catalyzed by silica-based HTMS-3A was studied in chemical engineering. Under the selected conditions，the conversion of allyl chloride reached 65.6%，the yield and selectivity of epichlorohydrin were 63.9% and 97.6%，the yield of glycerol and heavier by-products were1.5% and 0.2% respectively. The stability of silica-based HTMS-3A in epoxidation of allyl chloride was studied: the conversion of allyl chloride decreased from 65.6% to 58.9%.The activity of the deactivated catalyst may be recovered by washing with hot acetone，or by calcinations