Developing earth-rich highly efficient nonprecious electrocatalysts for hydrogen evolution reaction (HER) has become of great significance for sustainable energy technology. Herein, novel nickel foam (NF) supported porous featherlike NiCoP (PF-NiCoP/NF) nanoarrys are constructed by a successive hydrothermal and phosphidation way. Simultaneously, their three-dimensional (3D) morphology, the holey structure, and the conductive substrate are favorable for the enhanced specific surface area, efficient electron and mass transfer, and exposure of more active sites, and also are beneficial for the release of generated H2. PF-NiCoP/NF demonstrates high activity and long-term durability in alkaline media (1 M KOH) and real seawater, reaching the current density of 10 mA cm–2 at overpotentials of 46 and 287 mV, respectively. Moreover, the faradaic efficiency of 3D PF-NiCoP/NF is as high as 96.5% in real seawater. As expected, PF-NiCoP/NF exhibits superior performance in comparison to those of most of HER electrocatalysts in real seawater and alkaline media. This work may present a new strategy to design a promising electrocatalyst superior to platinum in a wide range of pH and may provide a new idea for electrocatalytic seawater splitting.

Dielectric film capacitors have aroused considerable attention on account of the fast development of pulsed power systems. However, enhanced energy density is always acquired at the cost of deteriorated charge/discharge efficiency. Herein, well balanced energy density and efficiency are achieved in a series of reasonably designed bilayer composites consisting of a ferroelectric layer and a paraelectric layer at the meantime. It is interesting to find that, when merely 1.6 wt% Zr(HPO4)2 nanosheets are introduced into the ferroelectric layer, a substantially improved energy density of 11.22 J cm−3, which is about 165% that of the bilayer composite without Zr(HPO4)2 nanosheets, is achieved at 650 kV mm−1. Meanwhile, a high charge/discharge efficiency of 89.8% and a low loss tangent of 0.024@10 kHz which is much lower than the pristine ferroelectric polymer layer (0.058@10 kHz) is maintained. Furthermore, finite element simulation reveals that the electric breakdown paths will develop along the macroscopical‐interfaces between adjoining layers and the microcosmic‐interfaces between the Zr(HPO4)2 nanosheets and polymer matrix, which can effectively increase the length of breakdown paths and contribute to improved breakdown strength. This work demonstrates that the Zr(HPO4)2 nanosheets can be promising fillers for other high‐performance dielectric composites.

Amorphous Fe-doped Co3(PO4)2 1D ultrathin nanowires manifest exceptional electrocatalytic performance owing to the synergistic interaction of 1D nanowire morphology, amorphous structure and Fe doping.

Climate change and land use/cover change (LUCC) have been widely recognized as the main driving forces that can affect regional hydrological processes, and quantitative assessment of their impacts is of great importance for the sustainable development of regional ecosystems, land use planning and water resources management. This study investigates the impacts of climate change and LUCC on variables such as streamflow (SF), soil moisture (SM) and evapotranspiration (ET) in the Guangdong-Hong Kong-Macao Greater Bay Area (GBA) by using Soil and Water Assessment Tools (SWAT) model under different scenarios during 1979–2018. The results show that the simulation performances were overall good, with Nash-Sutcliffe Efficiency Coefficient (NSE) and coefficient of determination (R2) greater than 0.80 for the monthly-scale SF calibration and validation. According to the results of trend and change point tests of meteorological series, the baseline period (1979–1997) and the interference period (1998–2018) were determined. Interestingly, other land use types were basically converted to urban land, leading to a rapid urbanization in the GBA. Compared with the SF values of the eight estuaries of the Pearl River Basin in the baseline period, both climate change and LUCC has led to the decrease in the SF values in the interference period, and the combined effect of climate change and LUCC was slightly greater than their individual effect. Overall, climate change and LUCC both have important impacts on regional hydrological processes in the GBA.

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