Photobiological chemicals production is of great importance for solar energy storage and clean fuel generation. One rising strategy for the solar fuels production is to enhance the non-photosynthetic cells’ original...
The selectivity of metal nanocatalysts is critical to the chemical transformations and industries. Herein, a highly selective heterogeneous living cell catalytic system (LCCS) with intracellular Pd nanodots (bio-nPd) via the...
The post-separation of powder catalysts restricts the practical application of peroxymonosulfate (PMS)-based advanced oxidation technology. Hence, we fabricated CuO-Fe2O3-modified Ni foam (CFO-NF) using a facile hydrothermal method for an efficient PMS activation. The CFO-NF/PMS system could achieve a 97.9% tetracycline hydrochloride (TC) removal efficiency in 60 min with four pieces of CFO-NF and 0.4 mmol L−1 of PMS. The removal efficiency was maintained at ˃85% even after five cycles, indicating the excellent stability of CFO-NF composites. The conversion among Fe(III)/Fe(II), Cu(II)/Cu(I), and Ni(III)/Ni(II) accelerated the PMS decomposition, verifying the synergy between CuO-Fe2O3 and Ni foam. The trapping experiments and EPR detection confirmed that abundant active species (•OH, SO4•−, O2•−, and 1O2) were produced in the CFO-NF/PMS system, accounting for the existence of radical pathways and a non-radical pathway, in which 1O2 (non-radical pathway) was dominated. This study developed a novel CuO-Fe2O3-modified Ni foam with a superior PMS activation performance, a high stability, and a recoverability for eliminating refractory organic pollutants.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.