A palladium-catalyzed reaction of aryl iodide-tethered alkenes with homoallyl alcohol is reported, providing a convenient and efficient approach to C(sp3)-allylation product. The cascade process involves intramolecular Heck/retro-allylation. This new approach...
A palladium-catalyzed cis-selective carboalkylation of internal alkynes with cyclobutanols is reported, providing a useful and facile approach to alkyl-substituted olefins in moderate to good yields with excellent stereoselectivity. The cascade...
A palladium-catalyzed reaction of homoallyl acohols with propargylic carbonates was realized via oxidative addition/decarboxylation/retro-allylation. The reaction proceeds with a wide substrate scope by using readily available starting materials, which provides...
A palladium/norbornene-catalyzed ortho-amination/allylation of aryl iodides was developed for the construction of ortho-aminated allylbenzene by using N-benzoyloxyamines as the amination reagent and homoallyl alcohols as the allylation reagent. The reaction...
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