Clean fuel technologies have been widely developed in current society because fuel combustion can directly bring about the emission of hazardous gasses, i.e. SO 2 , sulfate particulate matter (SPM), resulting in environmental pollution and other related problems that endanger public heath and community property; as well as reducing the life of the engine due to corrosion. The research efforts for developing conventional hydrodesulfurization (HDS) and alternative desulfurization methods such as selective adsorption, biodesulfurization, oxidation/extraction (oxidative desulfurization), etc. for removing these refractory sulfur compounds from liquid fuel products are on the rise. The reductive desulfurization method under ambient conditions has rarely been researched. This paper reviews the current status of various desulphurization techniques being studied worldwide. It presents an overview of novel emerging technologies of chemical and electrochemical reduction (CECR) for deep desulfurization of coal water slurry (CWS) so as to provide a new way of thinking about ultraclean fuel technology.
Diverse herbivores are known to induce various plant defenses. The plant defenses may detrimentally affect the performance and preference to subsequent herbivores on the same plant, such as affecting another insect’s feeding, settling, growth or oviposition. Here, we report two herbivores (mealybug
Phenacoccus solenopsis
and carmine spider mite
Tetranychus cinnabarinus
) which were used to pre-infest the cucumber to explore the impact on the plants and the later-colonizing species, whitefly
Bemisia tabaci
. The results showed that the whiteflies tended to select the treatments pre-infested by the mites, rather than the uninfected treatments. However, the result of treatments pre-infested by the mealybugs was opposite. Total number of eggs laid of whiteflies was related to their feeding preference. The results also showed that
T. cinnabarinus
were more likely to activate plant jasmonic acid (JA) regulated genes, while mealybugs were more likely to activate key genes regulated by salicylic acid (SA). The different plant defense activities on cucumbers may be one of the essential factors that affects the preference of
B. tabaci
. Moreover, the digestive enzymes and protective enzymes of the whitefly might play a substantial regulatory role in its settling and oviposition ability.
Pyraoxystrobin, (E)-2-(2-((3-(4-chlorophenyl)-1-methyl-1H-pyrazole-5-yloxy)methyl)phenyl)-3-methoxyacrylate, is a newly developed strobilurin fungicide with high antifungal efficiency. It has high potential to enter soil environments that might subsequently impact surface and groundwater. Therefore, C-labeled pyraoxystrobin was used as a tracer to study the adsorption/desorption and migration behavior of this compound under laboratory conditions in three typical agricultural soils. The adsorption isotherms conformed with the Freundlich equation. Single factor analysis showed that organic matter content was the most important factor influencing the adsorption. The highest adsorption level was measured in soil with low pH and high organic carbon content. Once adsorbed, only 2.54 to 6.41% of the adsorbed compound could be desorbed. In addition, the mobility results from thin-layer chromatography and column leaching studies showed that it might be safe to use pyraoxystrobin as a fungicide without causing groundwater pollution from both runoff and leaching, which might be attributed to its strong hydrophobicity. High organic matter content enhanced pyraoxystrobin adsorption and desorption because of the rule of similarity (lipid solubility). In the column leaching study, 95.02% (minimum value) of the appliedC remained within the upper 4.0-cm layer after 60 days.
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