We report superconductor and transport properties of a large class of tetragonal 1:2:3cuprates represented by the chemical formula (Ca R, ,)[Ba3, , R, «, &]Cu30, where R =La or Nd and existing as high-purity materials in a large range of z and x. At a given z, these materials maintain, through compensating cosubstitutions, a constant charge Q of the noncopper cations (Q =6+z) independent of x. By accurate control of oxygen content y, both cation and anion charge sources were kept constant. Under these isoelectronic conditions (constant electron concentration n) big changes in transition temperature T, , resistivity p and thermopower (TEP) S occur, suggesting that the microscopic hole density in the CuOz planes h changes. Having a single T, " (maximal T,), this material family behaves as a single material. Besides, for all values of Q, x, and y and for each R we show that T, , p, and 5 can each be represented by a single curve when plotted as a function of y -yM, (Q,x), where yM, denotes the value of y at the metal-insulator (M-I) transition. Therefore, there exists a one to one correspondence between h and y -yM &, but there is no straightforward relation between h and n We found a. n empirical formula describing the functional dependence of yM, on Q and x. This allows one to estimate yM &, T, , p, and S in many materials. Our results are interpreted in terms of a simple band picture which is modified to consider the existence of low-mobility states in the vicinity of EF . This accounts for the relatively low TEP at the M-I transition.
