Binary crystalline solids via solution casting under rapid drying conditions were found to show efficient triplet–triplet annihilation upconversion by suppressing the segregation of the components.

We report the synthesis and photochemical and photophysical properties of double alkylene-strapped 9,10-diphenylanthracene derivatives 3a-c (a: C6 strap, b: C7 strap, c: C8 strap) in which the reactive central aromatic ring of the anthracene moiety is protected by the double alkylene straps. Thus, 3a-c were much more resistant to photochemical reactions than the parent 9,10-diphenylanthracene (DPA). Furthermore, 3b in C6H12 as well as in a cast film and the powder state showed the highest fluorescence quantum yields among 3a, 3b, quadruple triethylsilyl-protected DPA 4, and DPA, wherein the C7 strap in 3b effectively serves to block fluorescence self-quenching.

Understanding of energetic particle (EP) confinement is one of the critical issues in realizing fusion reactor. In stellarator/helical devices, the research on EP confinement is one of the key topics to obtain better confinement by utilizing the flexibility of three-dimensional magnetic field. Study of EP transport in the Large Helical Device (LHD) has been performed by means of escaping EP diagnostics in hydrogen plasma operation. By starting deuterium operation of the LHD, confinement study of EPs has progressed remarkably by using newly developed comprehensive neutron diagnostics providing the information of EPs confined in the core region. The total neutron emission rate (Sn) increases due to the relatively low deviation of beam ion orbit from the flux surface with the inward shift of the magnetic axis. Sn has the peak around the electron density of 2×10 19 m -3 to 3×10 19 m -3 , as predicted. It is found that the fraction of beam-beam components in Sn is evaluated to be approximately 20% by the Fokker-Planck models TASK/FP in the plasma with both co-and counter-neutral beam injections. The equivalent fusion gain in DT plasma achieved 0.11 in a negative-ion-based neutral beam heated 2 plasma. Time evolution of Sn following the short pulse neutral beam injection into the electroncyclotron-heated low-beta plasma is reproduced by drift kinetic simulation, indicating that transport of beam ion injected by short pulse neutral beam can be described with neoclassical models in magnetohydrodynamic quiescent low-beta plasmas. The vertical neutron camera works successfully, demonstrating that in the co-neutral beam injected plasma, neutron emission profile shifts according to magnetic axis position. The shift of the neutron emission profile is reproduced by orbit-following models. The triton burnup study is performed for the first time in stellarator/heliotron so as to understand the alpha particle confinement. It is found that the triton burnup ratio, which largely increases at inward shifted configurations due to the better triton orbit and better plasma performance in inward shifted configuration is similar to that measured in tokamak having a similar minor radius with the LHD. We study the confinement capability of EPs toward a helical reactor in magnetohydrodynamic -quiescent region and expansion of the energetic-ion physics study in toroidal fusion plasmas.

FIDASIM is a code that models signals produced by charge-exchange reactions between neutrals and ions (both fast and thermal) in magnetically confined plasmas. With the ion distribution function as input, the code predicts the efflux to a neutral particle analyzer (NPA) diagnostic and the photon radiance of Balmer-alpha light to a fast-ion D α (FIDA) diagnostic, in addition to many other related quantities. A new, parallelized version of the Monte Carlo code FIDASIM has been developed in Fortan90 that is substantially faster than the original IDL version. Modified algorithms include more accurate treatments of the time dependent collisional-radiative equations that describe neutral energy levels, of the cloud of "halo" neutrals that surround the injected neutral beam, and of finite Larmor radius effects. Enhanced physics capabilities include modeling "passive" signals from cold edge neutrals, the ability to treat general three-dimensional magnetic confinement configurations, and calculations of diagnostic-specific weight functions that enable tomographic reconstructions of the fast-ion distribution function. Neutral beam attenuation, beam emission, and fast-ion birth profiles are also modelled. The new algorithms have been successfully validated against experimental data and new features have been tested through benchmarks between two independently developed versions of the code.