By tuning the structural phase transition in Zn2–xMgxP2O7, large negative thermal expansion (NTE) was achieved at room temperature. An earlier report described that Zn2P2O7 undergoes a structural phase transition at 405 K, accompanied by volume contraction of 1.8% on heating. Results showed that as Mg doping proceeds, the transition temperature decreases. Also, the volume change becomes gradual with respect to temperature. Particularly, Zn1.6Mg0.4P2O7 has a large negative coefficient of linear thermal expansion αL of −60 ppm/K at 280–350 K. Structural analysis using synchrotron radiation revealed that this dilatometric NTE is almost identical to that of crystallographic unit cells, indicating less dominant structural effects on NTE. We also verified thermal expansion compensation capabilities of powdered Zn1.6Mg0.4P2O7 by evaluating the thermal expansion of the epoxy resin matrix composites. The present phosphates are promising for use as practical thermal expansion compensators because they are free of toxic or expensive elements and can be fabricated in air using the simple solid-state reaction method.
We report the sol–gel synthesis of Cu2V2O7 fine particles, in which some of the constituent Cu is replaced with other elements. The sintered body of Zn substituted β-Cu1.8Zn0.2V2O7 shows a large negative thermal expansion (NTE) over a wide temperature range due to microstructural effects peculiar to a ceramic body. Using the sol–gel method, we successfully produced β-Cu1.8Zn0.2V2O7 ceramic fine particles that retain the same level of thermal expansion suppression capabilities as the bulk with a size of about 1 μm. We also succeeded in performing rare earth metal (Ce, Sm, Yb) substitutions, which might be a clue for improving NTE performance. These achievements provide particulate filler for thermal expansion control of a micrometer region, which has been earnestly sought in many fields of technology.
Public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing this collection of information. Send comments regarding this bunlen estimate or any other aspect of this collection of information, including suggestions for reducing this burden to Department of Defense, Washington Headquarters Services, Directorate for Information PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES)Air Force Research Laboratory/VSBXS 29 Randolph Road Hanscom AFB MA 01731-3010 PERFORMING ORGANIZATION REPORT NUMBER AFRL-VS-HA-TR-2004-1117 SPONSORING / MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR'S ACRONYM(S)AFRL/VSBXS SPONSOR/MONITOR'S REPORT NUMBER(S) DISTRIBUTION / AVAILABILITY STATEMENTApproved for Public Release; Distribution Unlimited.*Nagoya Univ, Toyokawa, JAPAN, **NOAA, Boulder, CO, ***Univ of Michigan, Ann Arbor, MI 13. SUPPLEMENTARY NOTES REPRINTED FROM: SPACE SCIENCE REVIEWS, Vol 107, pp 307-316, 2003, ABSTRACTAbstract. We report the recent progress in our joint program of real-time mapping of ionospheric electric fields and currents and field-aligned currents through the Geospace Environment Data Analysis System (GEDAS) at the Solar-Terrestrial Environment Laboratory and similar computer systems in the world. Data from individual ground magnetometers as well as from the solar wind are collected by these systems and are used as input for the KRM and AMIE magnetogram-inversion algorithms, which calculate the two-dimensional distribution of the ionospheric parameters. One of the goals of this program is to specify the solar-terrestrial environment in terms of ionospheric processes, providing the scientific community with more than what geomagnetic activity indices and statistical models provide. Abstract. We report the recent progress in our joint program of real-time mapping of ionosplneric electric fields and currents and field-aligned currents through the Geospace Environment Data Analysis System (GEDAS) at the Solar-Terrestrial Environment Laboratory and similar computer systems in the world. Data from individual ground magnetometers as well as from the solar wind are collected by these systems and are used as input for the KRM and AMIE magnetogram-inversion algorithms, which calculate the two-dimensional distribution of the ionospheric parameters. One of the goals of this program is to specify the solar-terrestrial environment in terms of ionospheric processes, providing the scientific community with more than what geomagnetic activity indices and statistical models provide. SUBJECT TERMS
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