An isotope of the 113th element, i.e., 278 113, was produced in a nuclear reaction with a 70 Zn beam on a 209 Bi target. We observed six consecutive decays following the implantation of a heavy particle in nearly the same position in the semiconductor detector under an extremely low background condition. The fifth and sixth decays are fully consistent with the sequential decays of 262 Db and 258 Lr in both decay energies and decay times. This indicates that the present decay chain consisted of 278 113, 274 Rg (Z 111), 270 Mt (Z 109), 266 Bh (Z 107), 262 Db (Z 105), and 258 Lr (Z 103) with firm connections. This result, together with previously reported results from 2004 and 2007, conclusively leads to the unambiguous production and identification of the isotope 278 113 of the 113th element.
Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)6 formulation.
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