The degree of weathering in natural stones on buildings and sculptures has been determined for many years in numerous cases by means of ultrasonic measurements. Conclusions concerning the strength of the rock and the type of weathering can thus be drawn. This relationship has not been established for all rock types. Most of the progress utilizing this method has been made in the analysis of marbles, where an increasing degree of weathering shows lower ultrasonic velocities. In the present study, four Carrara marble samples showing similar rock fabrics, but with respect to weathering exhibit considerable differences are investigated. Porosity varies between 0.2 vol. % and ca. 2.4 vol. %, whereby with increasing porosity the pore radii changes as well. Parallel to this the ultrasonic velocities change in dry samples from about 5.5 to 1.6 km/s, respectively. Model calculations reveal that the velocity reduction is caused by cracks with an extremely small aspect ratio of about 0.005 or even less. After a specific loss of strength, however, solution processes can become active, which modify the microcracks and generate an opposite trend. In the process a strong porosity increase correlates to a relatively small velocity reduction. With the presence of water the V p porosity weathering relationship experiences a considerable modification. Parallel to the reduction of the ultrasonic velocities, it was determined that the mechanical strength (compressive strength, flexural strength, etc.) as well as the static Young's modulus is reduced almost equally by a progressive advancement of the weathering front. In one case study dealing with tensile strengths, it was clearly documented how tensile cracks develop and propagate in dependence of the rock fabric. The rock mechanical and ultrasonic velocity data were used for stability assessments applied to the marble statuaries from the Schlossbrücke in Berlin. Stability assessments of the sculpture group 4 reveal that some critical parts must be replaced due to safety reasons.
After almost 200 years of exposure, the monuments of General Scharnhorst and Bülow have been analysed by means of ultrasound. Both sculptures are made of Carrara marble, both sculptures have been exposed to the same environmental influences and both sculptures are, based on the results of the ultrasonic measurements, in alarming conditions. This statement can be made because of the data of three different measurement investigations within the last 12 years. In this short exposure time, the already low velocities have been reduced by 16.2% and 14.7%. The very low average velocity of 2.8 km/s for the sculpture of General Bülow and a slightly higher average velocity of 3.2 km/s for the Scharnhorst sculpture indicate that both sculptures are in a poor condition, even though a protective winter shelter has been used since 2004. Comparing tomographic velocity measurements performed in 2006 with the measurements made in 2018 was possible and showed that even areas with a thickness up to 90 cm show alarming low ultrasonic velocities down to 2.6 km/s. Even if the circumstances for both sculptures have been the same, they differ in their weathering state. The careful and transparent documentation of all measurements was in this context the most important aspect for the comparative studies. Irregularities in their weathering behaviour of the two statues can be distinguished, allowing an in-depth analysis of the deterioration of the marble.
The present study documents the results of an inter-disciplinary model project that was planned with the aim of developing an innovative winter covering system for marble statuaries located on the Schlossbrücke (Berlin). Such a system would need to fulfil the various requirements for structural stability, aesthetics, climate and practical use. This applied research represents the first complex scientific study of the sustainability of a winter covering system. The study is characterised by the use of complex scientific instruments such as special laboratory analysis and numerical simulation tools. The interaction between the environment and the artefacts in connection with the innovative winter covering structures were studied by extensive climatic monitoring.
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