Reported here for the first time is the iodobenzene-catalyzed alpha-oxidation of ketones, in which diacyloxy(phenyl)-lambda3-iodanes generated in situ act as real oxidants of ketones and m-chloroperbenzoic acid serves as a terminal oxidant. Oxidation of a ketone with m-chloroperbenzoic acid in acetic acid in the presence of a catalytic amount of iodobenzene, BF3.Et2O, and water at room temperature under argon affords an alpha-acetoxy ketone in good yield. p-Methyl- and p-chloroiodobenzene also serve as efficient catalysts in this direct oxidation. We found that when the reaction was carried out in the absence of a catalytic amount of iodobenzene, Baeyer-Villiger oxidation of a ketone took place. It is noted that use of water and BF3.Et2O is crucial to the success of this alpha-acetoxylation.

Reference [15] should read as follows:[15] S. M. Bilenky and B.

Hyper-Kamiokande will be a next generation underground water Cherenkov detector with a total (fiducial) mass of 0.99 (0.56) million metric tons, approximately 20 (25) times larger than that of Super-Kamiokande. One of the main goals of Hyper-Kamiokande is the study of CP asymmetry in the lepton sector using accelerator neutrino and anti-neutrino beams.In this document, the physics potential of a long baseline neutrino experiment using the Hyper-Kamiokande detector and a neutrino beam from the J-PARC proton synchrotron is presented. The analysis has been updated from the previous Letter of Intent [K. Abe et al., arXiv:1109.3262 [hepex]], based on the experience gained from the ongoing T2K experiment. With a total exposure of 7.5 MW × 10 7 sec integrated proton beam power (corresponding to 1.56 × 10 22 protons on target with a 30 GeV proton beam) to a 2.5-degree off-axis neutrino beam produced by the J-PARC proton synchrotron, it is expected that the CP phase δCP can be determined to better than 19 degrees for all possible values of δCP , and CP violation can be established with a statistical significance of more than 3 σ (5 σ) for 76% (58%) of the δCP parameter space.

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Large-angle cross sections for yd-^ Tr^Jare systematically measured in the photon energy range between 500 and 1000 MeV. A good fit is obtained by use of a Glauber-model calculation which includes the dibaryon resonances ^F3(2.26) and ^G4(2.51), but the fit has an unusual nature in the role of resonance and nonresonance contributions.