In the title compound, C21H28O4·H2O, the cyclohexadienone ring is planar (r.m.s. deviation 0.0186 Å), whereas the two cyclohexane rings and the cyclohexanone ring adopt chair conformations. The crystal structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds.
The title compound C23H26O7, was prepared by esterification of 2-ethyl-7-hydroxy-8-methoxymethyl-4H-chromen-4-one with (S)-(−)-camphanic chloride. The two rings of the chromone system are coplanar, making a dihedral angle of 1.99 (19)°, and the camphanoyl unit substituted at 7-O retains the original bicyclo[2.2.1]heptane conformation of the starting reagent.
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