In this article, we describe an advance approach for the fabrication of chiral metal-oxide nanofilms. Our approach is based on the atomic layer deposition of titania and alumina nanofilms onto cellulose microfibers, used as chiral templates, leading to the formation of chiral nanofilms with a spatial fibrous structure. The chiral nanofilms were extensively characterized by X-ray photoelectron spectroscopy and high-resolution electron microscopy. The chiral property of the produced titania nanofilms was studied by enantioselective adsorption experiments using circular-dichroism spectroscopy and chiral high-performance liquid chromatography. We demonstrate the application of the titania chiral nanofilms for enantioselective crystallization. Overall, the basic principle for the preparation of chiral nanofilms by atomic layer deposition is demonstrated, as well as their uses for several enantioselective applications.

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In this communication, we describe the synthesis of new chiral alumina nanofilms and surfaces. Our method is based on chiral templating of alumina nanofilms by cellulose microfibers using the atomic layer deposition process. The chiral nature of the alumina nanofilms was characterized by a variety of techniques, such as quartz crystal microbalance, chiral circular-dichroism adsorption, chiral high-performance liquid chromatography and cyclic voltammetry measurements.

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