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The conversion of solar power to hydrogen (H 2 ) energy efficiently encounters some obstacles due to the lack of superior catalysts and efficient catalytic approaches. Herein, three-dimensional/ two-dimensional (3D/2D) CuS/g-C 3 N 4 photothermal catalysts were obtained via an easy, one-step hydrothermal method after pyrolysis. The favorable heterojunction interface for H 2 production was constructed by snowflake-like CuS embedded in the graphite carbon nitride (g-C 3 N 4 ) nanosheets, leading to the acceleration of charge transfer and separation, decrease of charge transfer distance, and perfect realization of photothermal effects (PTEs) induced by nearinfrared (NIR) light. The 3D/2D CuS/g-C 3 N 4 catalyst presents a topmost H 2 -production rate (1422 μmol h −1 g −1 ) under dual wavelength (420 + 850 nm) and a moderate H 2 -production rate under 420 nm, which are 12-fold and 9-fold higher than pure g-C 3 N 4 , respectively, owing to a strong action from PTEs induced by NIR. The feasible NIR-enhanced photothermal catalysis is expected to apply in multifarious heat-assisted photocatalysis processes by designing multifunctional composites with super PTE and photocatalytic capacity.

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