Making small liquid droplets move spontaneously on solid surfaces is a key challenge in lab-on-chip and heat exchanger technologies. Here, we report that a substrate curvature gradient can accelerate micro- and nanodroplets to high speeds on both hydrophilic and hydrophobic substrates. Experiments for microscale water droplets on tapered surfaces show a maximum speed of 0.42 m/s, 2 orders of magnitude higher than with a wettability gradient. We show that the total free energy and driving force exerted on a droplet are determined by the substrate curvature and substrate curvature gradient, respectively. Using molecular dynamics simulations, we predict nanoscale droplets moving spontaneously at over 100 m/s on tapered surfaces.
Biological nanochannels control the movements of different ions through cell membranes depending on not only those channels' static inherent configurations, structures, inner surface's physicochemical properties but also their dynamic shape changes, which are required in various essential functions of life processes. Inspired by ion channels, many artificial nanochannel‐based membranes for nanofluidics and biosensing applications have been developed to regulate ionic transport behaviors by using the functional molecular modifications at the inner surface of nanochannel to achieve a stimuli‐responsive layer. Here, the concept of a dynamic nanochannel system is further developed, which is a new way to regulate ion transport in nanochannels by using the dynamic change in the curvature of channels to adjust ionic rectification in real time. The dynamic curvature nanochannel‐based membrane displays the advanced features of the anomalous effect of voltage, concentration, and ionic size for applying simultaneous control over the curvature‐tunable asymmetric and reversible ionic rectification switching properties. This dynamic approach can be used to build smart nanochannel‐based systems, which have strong implications for flexible nanofluidics, ionic rectifiers, and power generators.
The friction brake works as an indispensable guarantee for regular work and safety operation of vehicles and industrial equipments. Friction and wear behaviors of brake's friction materials are considered as an important subject. In this article, friction materials were classified by matrix categories, and their major components were introduced first. Then, the advantages and disadvantages of each friction material were summarized and analyzed. Furthermore, the microcontacting behaviors on friction interface and the formation mechanism of various friction films were discussed. Finally, the influential rules and mechanism of braking conditions (temperature, pressure, and velocity) on the friction and wear behaviors of friction materials were summarized. It is concluded that the friction film, an intermediate product in braking, is greatly beneficial to protect friction materials from being seriously abraded. The braking conditions have complicated influences on friction and wear behaviors of brake. Generally, the friction coefficient tends to be fairly low while the wear rate increases rapidly under a condition with high temperature, braking pressure, or initial braking speed.
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