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Generally, a solution nucleation model is used to study biomineralization kinetics. However, we found that the amorphous calcium phosphate (ACP)-mediated hydroxyapatite (HAP) nucleation in simulated body fluids (SBF) had a different profile from the linear relationship between ln J and ln(-2) S (J, nucleation rate; S, supersaturation). This behaviour was alternatively explained by a developed heterogeneous nucleation theory, which indicated that HAP was nucleated at the ACP-solution interface via a polymorph transformation. Based upon this new model, we demonstrated experimentally that the embedded polymer molecules inside ACP were inert on HAP nucleation kinetics; rather, the polymers adsorbed on ACP surface could inhibit HAP nucleation from ACP. It further confirmed the heterogeneous nucleation pathway of HAP on the precursor phase. The present study provides an in-depth understanding of HAP formation for ACP-mediated crystallization.

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Functional finishing brings an alteration on the mechanical and surface properties of textile materials and henceforth influences the tactile properties. In this work, Kawabata evaluation systems (KES) for fabrics were utilized to notice the changes in the tactile properties of fabrics resulting from different finishing types such as inkjet printing, screen printing, and coating. The effects of functional finishing on the fabric’s tactile property were inconsistent with reference to the course of decrease or increase being dependent on the types of finishes. The findings showed that KES can be employed as a promising tool to sort out the suitable functional finishing types in terms of tactile properties. Amongst the implemented finishing types, inkjet printing offered superior tactile properties with respect to tensile energy (softness), shear rigidity, compressional softness, bending stiffness (drapability), and surface properties. The KES results confirmed that low-stress mechanical properties are strongly associated with the tactile property and might assist as a quality profile data source for guaranteeing the production and development of a virtuous quality product. The result encourages further utilization of the KES for functional fabric tactile property evaluation.

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