The conversion of CO(2) to valuable compounds, which is considered as an effective approach to solve the global warming, represents a great challenge due to the high stability and low reactivity of CO(2). Herein, thermodynamic calculations predicted the feasibility of exothermic reactions between CO(2) and Li(3)N into two important solid materials-carbon nitride and lithium cyanamide. Furthermore, the feasibility was confirmed by experiments, namely, the fast reaction between CO(2) and Li(3)N produced crystal lithium cyanamide and amorphous carbon nitrides. This provides a novel process to control CO(2) emissions.
It is generally recognized that the change of ZnO optical
properties
due to high-temperature treatment is reversible. However, herein,
it is reported that high-temperature treatment in air caused an irreversible
decrease in ZnO optical energy gap (E
g). The irreversible decrease in E
g was
enhanced with increasing treatment temperature. Furthermore, it was
found that the irreversible decrease in E
g can be attributed to the enlargement of ZnO crystal particles.
Mixtures of marine fish surimi and freshwater fish surimi might have synergistic gelation effects under certain conditions. Here, various mixtures of Nemipterus virgatus surimi and Hypophthalmichtys molitrix surimi were analyzed, with respect to gelation characteristics, rheological properties, protein conformations, and microstructure. When the ratio of N. virgatus surimi to H. molitrix surimi was 3:1, gel strength was increased by 3.08% and 92.13%, while cooking loss was reduced by 7.64% and 33.94%, as compared to pure N. virgatus surimi and pure H. molitrix surimi, respectively. In the mixed surimi as compared to the pure surimi, brightness and whiteness were improved, while water holding capacity, the elasticity modulus (G ), and the β-sheet content were increased. Three-dimensional (3D) network structure of the mixed surimi gel was more compact and uniform than that of either pure surimi gel. In a word, the elasticity modulus and β-sheet content of mixtures surimi were significantly increased, and the 3D structure was more compact and uniform; all these led to synergistic gelation effects in surimi mixtures composed of N. virgatus and H. molitrix.Practical Application: With the accelerated pace of life, the demand quantity of surimi products has increased year by year, but the main raw materials of marine fish resources are increasingly scarce. On the contrary, freshwater fish that can be used for surimi processing resources are very rich, and the price of them is low. Gel properties of freshwater fish surimi is worse than marine fish surimi, and how to improve it is one of the bottlenecks in the development of freshwater fish surimi. We and others have been found that the blended surimi from freshwater fish with marine fish could produce gel synergies under the proper conditions. So, Nemipterus virgatus (marine fish) surimi and Hypophthalmichtys molitrix (freshwater fish) surimi were used as raw materials, and the synergistic effects of the mixed surimi were explored.
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Food ChemistrySynergistic gelation effects in surimi mixtures . . .
Microstructure observationMicrostructure observations were made following Oujifard,
Highly dense AlN/CNT composite ceramics with 1-10% volume fractions of CNT were fabricated by spark plasma sintered (SPS) at 1400°C-1700°C. The results indicated that origination diameter of AlN had a great effect on microstructure and thermal conductivity. In details, for the system with AlN origination diameter of nanosized, the tubular structure of CNT has not been destructed, but when micro-sized AlN powder was adopted, the structure of CNT showed unstable at high temperature. Even though the degradation with incorporation of CNT into AlN, thermal conductivity of sintered AlN/CNT composites ceramics was evidently improved by adjusting content of additive Y2O3and the sintering process. Both the real part and imaginary part of the composites of Ka-Band (26.540.0 GHz) increase with the increase of CNT content, in which the increase of imaginary part is more than that of real part, resulting in an increase of loss factor. The AlN/ CNT thermal conductivity composites with appropriate CNT content and sintering temperature possess good dielectric dissipation and thermal conductivity.
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