Initiation of stress corrosion of X80 high strength low alloy (HSLA) pipeline steel in a near-neutral pH environment was investigated in a crevice cell simulating coating disbondment. Multi specimens were loaded simultaneously by a loading frame. EIS was applied to characterize behavior of SCC and local electrochemical process. Results indicate that the steel under disbonded coating is in an active dissolution state. In-depth profile of the reciprocal charge transfer resistance shows a decreasing trend over distance from the opening. A shielding factor was proposed to characterize shielding effect of disbondment on stress corrosion of pipeline steels.

The effect of urea on microbiologically induced corrosion (MIC) of carbon steel in soil was investigated using weight-loss measurement, electrochemical polarization, and electrochemical impedance spectroscopy (EIS). Urea tends to accelerate corrosion of carbon steel in inoculated soils and inhibit corrosion in sterile soils. In inoculated soils, FeS2 was detected in corrosion products because of the presence of sulfate-reducing bacteria (SRB). The EIS results showed that the process was controlled by concentration polarization in the later stages.

Stress corrosion cracking (SCC) has become one of the main threats for pipelines safe. The crack initiation is the first step for pipeline SCC. The disbonded coating affects the SCC initiation behavior. In the present paper, the effect of cathodic protection potential on SCC initiation for X70 pipeline steel in the NS4 solution beneath a disbonded coating is studied by a cyclic loading test. The SCC initiation situation was observed at the different distances beneath a disbonded coating area by SEM. The results show that the SCC initiation degree lightens with the increase of distance from the disbonded coating area under the condition of -850 mV cathodic protection potential. When the cathodic protection potential increases to -1000 mV, the SCC initiation degree slightly increases with the increase of distance from the disbonded position. But compared with that under the -850 mV, the crack initiation degree under -1000 mV is lower at the corresponding position. It is shown that the coating disbondment reduces the cathodic protection effect, and in order to obtain the same cathodic protection effect the cathodic protection potential should be appropriately moved in an negative way.