A dynamic liquid-phase microextraction technique combined with gas chromatography/mass spectrometry (GC/MS) is described for the extraction of 10 chlorobenzenes from water samples into 1 microL of organic solvent by using a conventional microsyringe. The effects of extraction solvent, plunger movement pattern, sampling volume, number of samplings, and salt concentration on the extraction performance were investigated. Good repeatabilities of extraction were obtained, with the RSD values below 5.3% except for hexachlorobenzene (9.3%). By using a sampling volume of 6 microL and 15 samplings, detection limits were found to be between 0.02 and 0.05 microgram/L under GC/MS-selective ion monitoring mode.
The Inner Tibetan Plateau (ITP; or called Qiangtang Plateau) appears to have experienced an overall wetting in summer (June, July and August) since the mid-1990s, which has caused the rapid expansion of thousands of lakes. In this study, changes in atmospheric circulations associated with the wetting process are analyzed for the years 1979 ∼ 2018. These analyses show that the wetting is associated with simultaneously weakened westerlies over the Tibetan Plateau (TP). The latter is further significantly correlated with the Atlantic Multidecadal Oscillation (AMO) on interdecadal time scales. The AMO has been in a positive phase (warm anomaly of the North Atlantic sea surface) since the mid-1990s, which has led to both a northward shift and weakening of the subtropical westerly jet stream at 200 hPa near the TP through a wave train of cyclonic and anticyclonic anomalies over Eurasia. These anomalies are characterized by an anomalous anticyclone to the east of the ITP and an anomalous cyclone to the west of the ITP. The former weakens the westerly winds, trapping water vapor over the ITP, while the latter facilitates water vapor intruding from the Arabian Sea into the ITP. Accordingly, summer precipitation over the ITP has increased since the mid-1990s.
Lake evaporation can influence basin-wide hydrological cycles and is an important factor in loss of water resources in endorheic lakes of the Tibetan Plateau. Because of the scarcity of data, published lake evaporation values are inconsistent, and their spatial distribution has never been reported. Presenting a plausible hypothesis of energy balance during the ice-free seasons, we explored the multiyear (2003–2016) average ice phenology and evaporation amounts of 75 large dimictic lakes by using a combination of meteorological and satellite data. Evaporation amounts show large variability in spatial distribution, with a pattern of higher values in the south. Lakes with higher elevation, smaller area, and higher latitude are generally associated with a shorter ice-free season and lower evaporation. The total evaporated water amounts have values of approximately 29.4 ± 1.2 km3 year−1 for the 75 studied lakes and 51.7 ± 2.1 km3 year−1 for all plateau lakes included.
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