In this paper, the hierarchical SnO2 nanostructures (HTNs) were prepared by a facile hydrothermal process. The prepared HTNs were characterized in detail by various analytical techniques that reveal the well-crystallinity with tetragonal rutile structure of SnO2 for the as-prepared material. By detailed experiments, interestingly, it was observed that the shapes and sizes of as-prepared HTNs could be tailored by varying the precursor concentration and reaction time. The synthesized HTNs were used as the efficient photocatalysts for the photocatalytic degradation of methylene blue (MB) under light illumination which showed almost complete degradation (∼99%) of MB dye in 20 min. The observed degradation for MB dye was higher than other commonly used dyes, i.e. methyl orange (MO; 96% in 50 min) and Rhodamine B (RhB; 97% in 40 min.). Further, the prepared HTNs were used as the effective gas sensing material to examine a series of volatile gases, such as ethanol, ammonia, benzene, acetone, toluene, methanol, diethyl ether, and methanol. By the detailed experiments, it was observed that the prepared HTNs exhibited tremendous gas sensing performance toward ethanol. Finally, because of the unique morphology and the fast ion and electron transfer characteristics, the prepared HTNs show excellent supercapacitor performances.
Electronic chirality near the Dirac point is a key property of graphene systems, which is revealed by the spectral intensity patterns as measured by angle-resolved photoemission spectroscopy under various polarization conditions. Specifically, the strongly modulated circular patterns for monolayer (bilayer) graphene rotate by ±90° (±45°) in changing from linearly to circularly polarized light; these angles are directly related to the phases of the wave functions and thus visually confirm the Berry's phase of π (2π) around the Dirac point. The details are verified by calculations.
Spin-polarized gapless surface states in topological insulators form chiral Dirac cones. When such materials are reduced to thin films, the Dirac states on the two faces of the film can overlap and couple by quantum tunneling, resulting in a thickness-dependent insulating gap at the Dirac point. Calculations for a freestanding Sb film with a thickness of four atomic bilayers yield a gap of 36 meV, yet angle-resolved photoemission measurements of a film grown on Si(111) reveal no gap formation. The surprisingly robust Dirac cone is explained by calculations in terms of interfacial interaction.
The long-term evolutionary interaction between the host immune system and symbiotic bacteria determines their cooperative rather than antagonistic relationship. It is known that commensal bacteria have evolved a number of mechanisms to manipulate the mammalian host immune system and maintain homeostasis. However, the strategies employed by the microbiome to overcome host immune responses in invertebrates still remain to be understood. Here, we report that the gut microbiome in mosquitoes utilizes C-type lectins (mosGCTLs) to evade the bactericidal capacity of antimicrobial peptides (AMPs). Aedes aegypti mosGCTLs facilitate colonization by multiple bacterial strains. Furthermore, maintenance of the gut microbial flora relies on the expression of mosGCTLs in A. aegypti. Silencing the orthologues of mosGCTL in another major mosquito vector (Culex pipiens pallens) also impairs the survival of gut commensal bacteria. The gut microbiome stimulates the expression of mosGCTLs, which coat the bacterial surface and counteract AMP activity. Our study describes a mechanism by which the insect symbiotic microbiome offsets gut immunity to achieve homeostasis.
Flowers are highly complex organs that have evolved to enhance the reproductive success of angiosperms. As a key component of flowers, petals play a vital role in attracting pollinators and ensuring successful pollination. Having fulfilled this function, petals senesce through a process that involves many physiological and biochemical changes that also occur during leaf senescence. However, petal senescence is distinct, due to the abundance of secondary metabolites in petals and the fact that petal senescence is irreversible. Various phytohormones are involved in regulating petal senescence, and are thought to act both synergistically and antagonistically. In this regard, there appears to be developmental point during which such regulatory signals are sensed and senescence is initiated. Here, we review current understanding of petal senescence, and discuss associated regulatory mechanisms involving hormone interactions and epigenetic regulation.
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