The decoration of noble metal nanoparticles (NPs) on the surface of metal oxide semiconductors to enhance material characteristics and gas-sensing performance has recently attracted increasing attention from researchers worldwide. Here, we have synthesized porous silicon (PS)/WO3 nanorods (NRs) functionalized with Pd NPs to enhance NO2 gas-sensing performance. PS was first prepared using electrochemical methods and worked as a substrate. WO3 NRs were synthesized by thermally oxidizing W film on the PS substrate. Pd NPs were decorated on the surface of WO3 NRs via in-situ reduction of the Pd complex solution by using Pluronic P123 as the reducing agent. The gas-sensing characteristics were tested at different gas concentrations and different temperatures ranging from room temperature to 200 °C. Results revealed that, compared with bare PS/WO3 NRs and Si/WO3 NRs functionalized with Pd NPs, the Pd-decorated PS/WO3 NRs exhibited higher and quicker responses to NO2, with a detection concentration as low as 0.25 ppm and a maximum response at room temperature. The gas-sensing mechanism was also investigated and is discussed in detail. The high surface area to volume ratio of PS and the reaction-absorption mechanism can be explained the enhanced sensing performance.
We present a narrow linewidth, all-fiber polarization-maintained amplifier chain seeded by a phase-modulated single-frequency laser, which is a narrow linewidth. Different from previous phase-modulation techniques, the phase-modulation signal is generated by simply imposing an excited signal to an acoustic-optical driven source. Theoretical simulation results show that this method can suppress stimulated Brillouin scattering (SBS) to a better degree, and the output power can be boosted to about 1.2 kW in terms of the SBS threshold. By amplifying the phase-modulated seed based on master-oscillator power-amplification configuration in experiments, a 560 W output laser is achieved with slope efficiency of 87.2% and linewidth of <5 GHz. Further power scaling is limited by mode instability instead of an SBS effect. At maximal output power, the beam quality (M2 factor) and polarization extinction ratio is measured to be within 1.3 and 14 dB, respectively.
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