Monitoring the condition of transformer oil is considered to be one of the preventive maintenance measures and it is very critical in ensuring the safety as well as optimal performance of the equipment. Various oil properties and contents in oil can be monitored such as acidity, furanic compounds and color. The current method is used to determine the color index (CI) of transformer oil produces an error of 0.5 in measurement, has high risk of human handling error, additional expense such as sampling and transportations, and limited samples can be measured per day due to safety and health reasons. Therefore, this work proposes the determination of CI of transformer oil using ultraviolet-to-visible (UV-Vis) spectroscopy. Results show a good correlation between the CI of transformer oil and the absorbance spectral responses of oils from 300 nm to 700 nm. Modeled equations were developed to relate the CI of the oil with the cutoff wavelength and absorbance, and with the area under the curve from 360 nm to 600 nm. These equations were verified with another set of oil samples. The equation that describes the relationship between cutoff wavelength, absorbance and CI of the oil shows higher accuracy with root mean square error (RMSE) of 0.1961.

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The condition of a power transformer can be predicted based on the contents of the transformer oil. One of the most common parameters that are observed in the transformer oil is 2-Furaldehyde, a compound that is produced due to the aging of Kraft paper. Although the optical characterization of 2-Furaldehyde has been widely reported, the fundamental theories of the observation of the optical absorbance peaks have not been elaborated. This study investigates the optical characteristics of 2-Furaldehyde in the near infrared region. Ten samples with different concentrations of 2-Furaldehyde were prepared and verified using the conventional method. The samples were then characterized using optical spectroscopy method with 50 mm path length cuvettes. Three peaks were observed at 1610 nm-1640 nm, 1100 nm-1115 nm and 860 nm-890 nm wavebands and were correlated to the overtones of the aromatic C-H stretch in 2-Furaldehyde. The appearance of these overtones corresponding to the Morse Oscillation Theory was discussed. This fundamental knowledge is significant in developing a portable optical device that enables the detection of 2-Furaldehyde on site.

For most natural or naturally-derived liquid products, their color reflects on their quality and occasionally affects customer preferences. To date, there are a few subjective and objective methods for color measurement which are currently utilized by various industries. Researchers are also improving these methods and inventing new methods, as color is proven to have the ability to provide various information on the condition and quality of the liquid. However, a review on the methods, especially for amber-colored liquid, has not been conducted yet. This paper presents a comprehensive review on the subjective and objective methods for color measurement of amber-colored liquids. The pros and cons of the measurement methods, the effects of the color on customer preferences, and the international industry standards on color measurements are reviewed and discussed. In addition, this study elaborates on the issues and challenges related to the color measurement techniques as well as recommendations for future research. This review demonstrates that the existing color measurement technique can determine the color according to the standards and color scales. However, the efforts toward minimizing the complexity of the hardware while maximizing the signal processing through advanced computation are still lacking. Therefore, through this critical review, this review can hopefully intensify the efforts toward finding an optimized method or technique for color measurement of liquids and thus expedite the development of a portable device that can measure color accurately.