Silicon is receiving significant
attention among different anode
materials for Li-ion batteries due to its superhigh theoretical energy
density. However, the commercial application of Si anode is facing
huge obstacles because of the inferior electrical conductivity, the
pulverization arising from the volume change, and the high cost of
nanosilicon. Herein, we demonstrate a facile method to achieve excellent
performance by in situ growing vertical graphene shell on microsilicon.
The vertical graphene nanosheets can be conformally grown on porous
microsilicon particles embedded with nanosilver particles to form
the graphene-encapsulated porous Si@Ag particles (VG-PMSi@Ag). The
unique structure integrates high conductivity and flexibility, which
accelerate the charge transport and accommodate the volume change
of silicon during the cycling process. As a result, the batteries
exhibit a high initial discharge capacity of 3121.6 mAh·g–1 at 0.1 A·g–1 and a high rate
capability of 943.8 mAh·g–1 at 6 A·g–1. A high reversible capacity of 1403.9 mAh·g–1 at 2.0 A·g–1 after 100 cycles
is achieved. This approach offers insights into the fabrication of
silicon anodes for high-performance lithium-ion batteries.
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