Water exhibits rich phase behaviors in nanoscale confinement. Since the simulation evidence of the formation of single-walled ice nanotubes (INTs) in single-walled carbon nanotubes was confirmed experimentally, INTs have been recognized as a form of low-dimensional hydrogen-bonding network. However, the single-walled INTs reported in the literature all possess subnanometer diameters (<1 nm). Herein, based on systematic and large-scale molecular dynamics simulations, we demonstrate the spontaneous freezing transition of liquid water to single-walled INTs with diameters reaching ∼10 nm when confined to capillaries of double-walled carbon nanotubes (DW-CNTs). Three distinct classes of INTs are observed, namely, INTs with flat square walls (INTs-FSW), INTs with puckered rhombic walls (INTs-PRW), and INTs with bilayer hexagonal walls (INTs-BHW). Surprisingly, when water is confined in DW-CNT (3, 3)@(13, 13), an INT-FSW freezing temperature of 380 K can be reached, which is even higher than the boiling temperature of bulk water at atmospheric pressure. The freezing temperatures of INTs-FSW decrease as their caliber increases, approaching to the freezing temperature of two-dimensional flat square ice at the large-diameter limit. In contrast, the freezing temperature of INTs-PRW is insensitive to their diameter. Ab initio molecular dynamics simulations are performed to examine the stability of the INT-FSW and INT-PRW. The highly stable INTs with diameters beyond subnanometer scale can be exploited for potential applications in nanofluidic technologies and for mass transport as bioinspired nanochannels.

The history of scientific research on diverse ice structures has been more than a century. To date, 20 three-dimensional crystalline ice phases (ice I-ice XX) have been identified in the...