Both X-ray imaging and neutron imaging are essential methods in non-destructive testing. In this work, a bimodal imaging method combining neutron and X-ray imaging is introduced. The experiment is based on a compact electron accelerator that can simultaneously generate two kinds of radiation: X-ray and neutron. This identification method utilizes the attenuation difference of the two rays’ incidence on the same material to determine the material’s properties based on dual-imaging fusion. It can enhance the identification of the materials from single ray imaging and has the potential for widespread use in on-site, non-destructive testing where metallic materials and non-metallic materials are mixed.