S emiconductor nanowires are the fundamental materials for fabricating a wide range of nanodevices. 1Ϫ5 In the oxide family, ZnO nanowires and nanobelts have been widely studied as a key 1D oxide nanomaterial for numerous applications. Due to the unique piezoelectric and semiconducting coupled properties, a range of novel nanodevices of ZnO have been developed, such as nanogenerators, 6Ϫ9 piezoelectric field effect transistors, 10 piezoelectric diode, 11 and strain sensors. 12 A direct band gap of 3.4 eV and a large exciton binding energy (60 meV) at room temperature make ZnO a prominent candidate in optical applications, such as an ultraviolet detector, 13Ϫ16 optical pumped laser, 17,18 and light emitting diodes. 19 Recently, the photoconducting response at different degrees of straining of a ZnO nanowire has been studied using in situ transmission electron microscopy. 20 Although a lot of progress has been made in each research field as stated above, very limited research has been conducted on the localized and quantitatively controlled coupling of the piezoelectric effect and photoexcitation on a ZnO nanowire nanodevice.In this paper, by introducing a controllable stepping strain and using a focused laser beam, we have investigated the localized coupling between the piezoelectric effect and photoexcitation of ZnO microwire devices that exhibit various controlled electrical transport characteristics. By using microwire devices with SchottkyϪOhmic, OhmicϪOhmic, and SchottkyϪSchottky contacts, we have demonstrated the finetuning of contact characteristics, such as from Schottky to Ohmic or from Ohmic to Schottky, by varying the individual contributions made by piezoelectricity and photoexcitation at local contacts. On the basis of this concept, a design of electric transport properties is demonstrated. This study reveals a new principle for controlling the coupling among mechanical, electrical, and optical properties, which can be the basis for fabricating piezo-photonic-electronic nanodevices, which is referred to as piezophototronics.
RESULTS AND DISCUSSIONOur device was fabricated using a single micro/nanowire of ZnO (see the Experimental Methods for details). First, we investigated the photoresponse of a microwire device with photoexcitation at different locations along the ZnO microwire. Figure 1a is a superimposed optical image taken from a ZnO microwire device with the laser spot focused at different positions, as schematically shown on the right-hand side. Points P1, P2, and P3, respectively, represent the positions at the left-hand metalϪZnO contact, central channel region, and right-hand metalϪZnO contact.