With the rapid development of economic globalization, a new type of mobile learning mode has emerged. Currently, the life of contemporary college students is inseparable from cell phones and computers, and such electronic devices are considered the important medium of mobile learning in the second classroom. In the process of education reform and “Internet +” integration, the blended teaching mode relying on the mobile network environment is favored by college English teachers. Furthermore, to improve the quality of English teaching, English teachers use the flipped classroom format to fully integrate the traditional classroom with online courses. In such format, a comprehensive, diversified assessment and evaluation system is built effectively. Specifically, starting from the current situation of college English teaching, the article analyzes and researches the flipped classroom hybrid teaching mode in four aspects to provide reference values for related scholars. Considering mentioned characteristics and advantages, the necessity and feasibility of adopting mobile learning mode in the second classroom teaching of college English are analyzed in this paper. Meanwhile, the application mode of specific devices for better learning is considered for better learning.