Inspired by the structures of enzymes, a fast and robust strategy for generating ZIF-90 metallo-nanozyme is presented. The Zn-N coordination structure in the ZIF-90 can closely imitate the catalytic center...
Barbecue smoke, car exhaust, cigarette smoke, and other waste gases contain toxic reactive oxygen species (ROS) and polycyclic aromatic hydrocarbons (PAHs). Herein, CeO 2 -based porous carbonaceous frameworks (CeO 2 PCFs) were explored as antioxidant nanozymes to scavenge ROS and absorb benzo[a]pyrene (B[a]P). Using cerium-based frameworks as the precursors, CeO 2 PCFs were constructed by high-temperature calcination. Due to excellent superoxide dismutase-like and catalase-like activity, CeO 2 PCFs could effectively eliminate superoxide radical, hydroxyl radical, and hydrogen peroxide. The 2,2′-azino-bis (3ethylbenzthiazoline-6-sulfonic acid) free radical scavenging assay had substantiated free radical scavenging ability of CeO 2 PCFs. In addition, with a large surface area and porous structure, CeO 2 PCFs could adsorb B[a]P efficiently. The designed CeO 2 PCFs may provide a new opportunity as scavengers of ROS and absorbents of PAHs in some harmful gases.
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