State‐of‐the‐art photodetectors which apply hybrid perovskite materials have emerged as powerful candidates for next‐generation light sensing. Among them, lead‐based ones are the most popular beyond doubt on account of their unique and superior optoelectronic properties. Nevertheless, trade‐off toward commercialization exists between nontoxicity and high performance, with the poor stability of lead‐based perovskites, indicating that it is indispensable to substitute lead with nontoxic element meanwhile bringing about a comparable figure of merit of photodetectors and relatively long‐term stability. Herein, recent advances in lead‐free perovskite photodetectors are reviewed, analyzing the principle while designing new materials and highlighting some remarkable progress, which are comparable, even superior, to lead‐based photodetectors. Furthermore, their potential strategy in optical communication, image sensing, narrowband photodetection, etc., is examined and a perspective on developing new materials and photodetectors with superior properties for more practical applications is provided.

Organic–inorganic hybrid perovskite (OIHP) photodetectors have presented unprecedented device performance mainly owing to outstanding material properties. However, the solution‐processed OIHP polycrystalline thin films with defective surface and grain boundaries always impair the key parameter of photodetectors. Herein, a nonfullerene passivation layer exhibits more efficient passivation for OIHP materials to dramatically reduce the trap density of state, yielding a dark current as low as 2.6 × 10−8 A cm−2 under −0.1 V. In addition, the strong absorption in near‐infrared (NIR) region of nonfullerene/C60 heterojunction broadens the detectable range to over 900 nm by effective charge transport, ultimately leading to a specific detectivity of 1.45 × 1012 and 7.37 × 1011 cm Hz1/2 W−1 at 650 and 820 nm, respectively. Encouragingly, the response speed of 27 ns is obtained at 0.6 mm2 of device area by removing constrain from the resistance–capacitance constant. Moreover, the prominent practical application of the photodetector is demonstrated in a weak light detection circuit and a visible light communication system. It is believed that the OIHP photodetectors with high sensitivity, NIR photoresponse, and ultrafast speed would pave the way to commercial applications.

Perovskite photodetectors have gradually shown preeminent photoelectric performance due to the unique material properties. In recent years, lots of works have been reported in improving the sensitivity, changing detection spectrum range and enhancing long‐term stability. Herein, we summarize the some efficient strategies for performance improvement and synchronously analyze severe issues exposed in that. Furthermore, some reasonable proposals are put forward to solve future predicted troubles. In addition, more prospective assumptions are proposed on the basis of the development trend in photoelectric detection fields. We hope this perspective will allow researchers to have a clearer understanding of recent studies based on perovskite photodetectors and inspire more meaningful work in the future.