Three-dimensional (3D) laser nanoprinting allows maskless manufacturing of diverse nanostructures with nanoscale resolution. However, 3D manufacturing of inorganic nanostructures typically requires nanomaterial-polymer composites and is limited by a photopolymerization mechanism, resulting in a reduction of material purity and degradation of intrinsic properties. We developed a polymerization-independent, laser direct writing technique called photoexcitation-induced chemical bonding. Without any additives, the holes excited inside semiconductor quantum dots are transferred to the nanocrystal surface and improve their chemical reactivity, leading to interparticle chemical bonding. As a proof of concept, we printed arbitrary 3D quantum dot architectures at a resolution beyond the diffraction limit. Our strategy will enable the manufacturing of free-form quantum dot optoelectronic devices such as light-emitting devices or photodetectors.

Vol. 44 , No,12(1988) 615 a) Extracted with 95% ethanol for 6 hr. b) In PhOH(50)-TCE(50) at 25°C.

The inherent defects of recycled aggregate concrete (RAC) include the complex interfacial transition zone (ITZ) and the many micro-cracks that appear during its producing process, which result in some inferior mechanical properties compared with natural aggregate concrete (NAC). This drawback usually prevents RAC from being selected for structural purposes. Existing research has shown that the strength and ductility of damaged concrete in compression members can be significantly enhanced through external confinement using fiber-reinforced polymer (FRP) wraps. This application has been widely used in concrete structural repair and retrofitting technology. However, research on the effects of RAC damage coupled with different load damage conditions is rare, as is information on the mechanical properties of RAC reinforced with FRP jackets. This paper presents the results of an experimental study on the behavior of pre-damaged recycled aggregate concrete cylinders that were repaired with carbon fiber-reinforced polymer (CFRP) or large rupture strain (LRS)-FRP jackets. Tests were conducted on 58 concrete cylinders with variations in the replacement ratio, damage levels, and FRP properties. Test results demonstrated that the ultimate strain and strength of damaged recycled aggregate concrete could be significantly enhanced by FRP jackets and that aggregate quality plays a vital role in the strength of confined concrete. Also, the energy absorption of CFRP- and LRS-FRP-confined RAC were evaluated. The analysis indicated that, compared with CFRP-confined RAC, LRS-FRP can greatly improve the energy absorption capacity of RAC; thus, LRS-FRP confined concrete has a good potential to achieve a ductile design for concrete columns, especially when used in seismic reinforcement.

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