A nanocube is a single nanoscale crystal with a cubic shape. Raw materials are an important factor in determining the synthesis of nanocubes. In this study, we investigated various niobium compounds that serve as raw materials, each inducing different effects during nanocube synthesis. Perovskite sodium niobate (NaNbO 3 ) nanocubes were synthesized using a two-step process. The first step in this process, synthesis of the raw materials, was followed by solvothermal synthesis of NaNbO 3 nanocubes. The raw material for the first step was obtained by applying heat treatment to a precursor following Nb hydrolysis. The heat treatment was performed at temperatures of 300-1000°C. Nb 2 O 5 was obtained after heat treatment of its precursor, during which its crystalline system morphed into hexagonal, orthorhombic, and monoclinic systems with respective increases in temperature. For the second step, we obtained various NaNbO 3 morphologies via the solvothermal method using water, methanol, or ethanol as a reaction medium. NaNbO 3 nanocubes were formed by applying the solvothermal method to the synthesized precursor during heat treatment at 800°C. Solvothermal synthesis was performed with methanol as the reaction medium at 200°C, which resulted in the formation of NaNbO 3 nanocubes. ARTICLE HISTORY

NaNbO 3 particles were prepared by solvothermal synthesis at 230°C in a reaction medium of either water or methanol. Morphological control of the particles was achieved by varying the synthesis conditions, such as the starting material and the reaction medium. The starting material was prepared by a process involving heat treatment of an Nb precursor at 400°C and 800°C. The crystal structure of the starting material depended on the heat treatment temperature, with the preferred orthorhombic Nb 2 O 5 obtained at 800°C. Large particles were obtained when water was used as the reaction medium, whereas fine particles were obtained using methanol. Under appropriate conditions, NaNbO 3 nanocubes can be synthesized using orthorhombic Nb 2 O 5 as the starting material and methanol as the reaction medium.